含二级供电基团的三聚茚基光敏染料的合成及其光伏性能研究-药物化学专业论文.docxVIP

Ab Abstract Abstract Nowadays, solar energy, clean, green, and polution-free, has drawn much of people’s interest as energy is runnning out and environmental polution is becoming increasingly serious.Significant attention has been attracted by dye sensitized solar cells (DSSCs) as alternatives to traditional solar cells, owing to their low-cost fabrication combined with high photovoltaic performance. Triphenylamine (TPA) and their derivatives are well-known electron-rich compounds that are widely used in various optical and electronic fields. Here, three new asymmetric truxene based triarylamine organic dyes (M40-M42) featuring TPA or dihexyloxy-substituted triphenylamine (DHO-TPA) or hexyl-phenothiazine（H-PTZ）as one electron donor and truxene unit as another electron donor have been designed and synthesized. The introducing of the bulky segment of hexalkyl-substituted truxene group featuring a three-dimensional configuration into a push–pull dye exhibits fairly good photovoltages in cobalt cells. A result due mainly to the retards the rate of interfacial back electron transfer from the conduction band of the titanium dioxide film to the electrolyte. 2+/3+ 2+/3+ Two cobalt electrolytes (Co(phen)3 , Co(bpy)3 ) has been introduced to the dye sensitized solar cells in this research,and the relationship between photovoltaic performance and dye structure is stuied. The main reaction is Buchwald-Hartwig reaction, Vilsmeier-Haack reaction and Knoevenagel condensation reaction, etc. The main intermediates and target product have been characterized by modern analytical tools such as NMR and MS, etc. Absorption spectra, electrochemical measurements, theoretical calculations, and photovoltaic measurements are used to compare the light absorptions, energy-levels, and charge transfer dynamics that contribute to the photovoltaic behavior. UV/Vis absorption spectra of the resulting dyes indicate that all of the there dyes have a relatively broad and strong absorpti