海洋大气环境下混凝土氯离子侵蚀性能的试验研究-结构工程专业论文.docxVIP

西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 西安建筑科技大学硕士学位论文 海洋大气环境下混凝土氯离子侵蚀性能的试验研究 专 业：结构工程 硕 士 生：齐广政 指导教师：牛荻涛 教授 摘 要 混凝土中的钢筋锈蚀是造成混凝土结构耐久性损伤的最主要因素，而氯离子 侵蚀和碳化则是混凝土中钢筋锈蚀的主要诱因。海洋大气区存在氯离子侵蚀和碳 化双重劣化机制，两种劣化机制相互影响产生的叠加效应加速了混凝土结构性能 劣化，因此，开展海洋大气环境下混凝土中氯离子侵蚀规律研究具有重要的现实 意义。 本文采用盐雾腐蚀环境模拟海洋大气环境，深入研究了水胶比、粉煤灰掺量、 碳化作用以及盐雾腐蚀时间对氯离子浓度分布和氯离子扩散系数的影响，通过电 镜扫描试验和压汞试验，从微观的角度分析了水胶比、粉煤灰掺量、碳化作用对 氯离子侵蚀的影响。研究结果表明：（1）减小水胶比可显著降低混凝土的氯离子 扩散系数及自由氯离子浓度；（2）当粉煤灰掺量在 30%以内时，混凝土的抗氯离 子侵蚀性能随粉煤灰掺量的增大而提高；（3）对于水胶比较高的普通混凝土和掺 加粉煤灰的混凝土，碳化使得混凝土多害孔体积增多，临界孔径和最可几孔径增 大，孔隙曲折度降低，连通性提高，有害物质更容易侵入混凝土内部，因此，加 速碳化后，混凝土的氯离子浓度及扩散系数均有所增大。 关 键 词：混凝土；海洋大气；氯离子；碳化；电镜扫描；压汞 论文类型：应用基础研究 基金项目：国家杰出青年科学基金项目 Experimental Research on Chloride Ion Erosion of Concrete in the Marine Atmospheric Environment Specialty: Structural Engineering Candidate: Qi Guangzheng Supervisor: Prof. Niu Ditao ABSTRACT Steel corrosion in concrete is the main factor causing durability damage to the concrete structure, concrete carbonation and chloride ion erosion is a major cause of corrosion of steel bars in concrete. The concrete structures in the marine atmospheric environment are subjected to coupling action of the salt spray corrosion and carbonation, and the concrete structures in the marine atmospheric are more susceptible to reinforcement corrosion. Therefore, carrying out the research on the chloride ion in concrete in the marine atmosphere is of practical significance. In this paper, salt spray corrosion environment was used to simulate marine atmosphere. The effects of water-binder ratio, content of fly ash, carbonation and salt spray corrosion time on distribution of chloride concentration and chloride ions diffusion coefficient were deeply studied. The effects of water-binder ratio, content of fly ash, carbonation and salt spray corrosion time on chloride ion penetration were revealed from the microscopic point of view by SEM and MIP. The results show that: (1) Decrease of water-cement ratio can significantly reduce the concrete chloride io