含光致变色结构的金属化合物与大环化合物的合成及性质研究-有机化学专业论文.docxVIP

⑨DOCTORALDISS。一的光致变色性质。重点讨论了八神不同的金属离子对化合物光致变色性质的影响。结果表明金属汞离子能够使化合物的开关行为被锁定在开环状态或闭环状态而不受光的控制，而当加入EDTA后，化合物又能重新发生光致变色反应，同时还发现其它的大多数金属离子对化合物的光致变色性质都会产生一定的影响；6、第六章中以氯取代的二噻吩基乙烯作为原料，合成了3个二噻吩基乙烯类大环化合物。通过lqMR、X-ray以及质谱等表征了它们的结构，重点讨论了化合物的光致变色性能．结果表明由三个二噻吩基乙烯结构单元组成的大环化合物具有非常高的开环量子收率、良好的热稳定性和优秀的抗疲劳性。关键词：光致变色；偶氮苯：二噻吩基乙烯：金属化合物；大环化合物；开关行为AbstractInrfoeqltyears，therehasbeenconfrontedwithhigherchallengealongwiththeffequentdevelopmentofthescienceofinformationandrelatedtechnologyinthefieldofthemicro-processor．Inordertoovercomethephysicalandtechnologiclimits，somefunctionalmicro-devicessuchasmolecularwires,molecularswitches,molecularrectifiersandmolecularstorageshavebeendesignedandmanufacturedinmoleculeIevels．SostudiesonmoleculardovJccshaverecdvedmuchattentationfromthescientistswhoworkOnchemistryandscienceofmaterialatpresenLBasiccomponentsofmoleculardevicesareinformationstoragematerialswithphotochromicpropemes．Toexploreofnovelstructuresanduniqueproperties，someorganometalliccompoundsandmacrocycleswitho，o-bridgingazobenzenechainsanddithienyletheneunitsWeredesignedandsynthesized,andtheircharacterization,photochromicpropertieswillbedescribedasfollowing1．111cphotochromismandrelatedconceptsweredescribed,andtherecentprogressinthefieldsoftheazoanddithienylethenesystemswassummarized．Furthermore,the(’．MbondWasintroducedintothesetwosystemsandtheuniqueshaped-modulatedmacrocyclcsworosynthesized．2．The4,4-diethynylazobenzeneWasusedasthestartingmaterial，whichWaslrcatedwithmetallicrutheniumreagentandotherligandstogivesixbimetallicrutheniumcompoundswitho,o-bridgingazobenzenecbains．TheirslructuresweroconfmnedbyNMR,X-raycrystaldiffTactionandelementalanalysis,andtheirdeclxochemicalproperties,photoisomerizationpropertiesandbehaviorofswitchweredescribed．TheresultsindicatedgoodphotoisomerizationpropertiesandeffectsbetweenmetalatomandmetalatomeachotheL3．111cdiformyl-substitudeddithienyletheneWasusedasthestartingmaterial,andsixdithienylethenedefiva6veswithferruceneunitsworosynthesizedthroughWittigresctionsandAl