界面聚合反应制备中空纤维纳滤膜的数学模型-中南大学学报.PDF

第 40 卷第 2 期 中南大学学报( 自然科学版) Vol.40 No.2 2009 年 4 月 Journal of Central South University (Science and Technology) Apr. 2009 界面聚合反应制备中空纤维纳滤膜的数学模型 刘久清，李新海，王志兴，刘婉蓉 ( 中南大学 冶金科学与工程学院，湖南 长沙，410083) 摘 要：采用界面聚合反应成膜机理制备中空纤维纳滤膜，建立在非稳态条件下化学反应－扩散控制的数学模型， 并通过有针对性的简化，使该模型适用于扩散控制。以哌嗪－三乙胺水溶液作为水相，均苯三甲酰氯作为有机相 单体，甲苯作为有机相溶剂进行界面聚合反应制备中空纤维膜，进而通过实验对数学模型进行验证。研究结果表 明：通过模型计算，在反应达到 10 s 时，复合膜的厚度约为 0.9 μm ；从实验中甲苯体系反应 10 s 后得到的扫描电 镜照片可以看到，此时复合膜的厚度为 1 μm 左右，说明界面聚合反应成膜原理能正确地指导建立数学模型；模 型预测值与实验数据基本吻合；所建立的数学模型能够较好地揭示界面聚合反应成膜过程的实质。 关键词：复合膜；界面聚合；中空纤维膜；数学模型 中图分类号：TQ018 文献标识码：A 文章编号：1672−7207(2009)02−0294−05 Mathematic model for formation of hollow fiber nanofiltration membrane by interfacial polymerization LIU Jiu-qing, LI Xin-hai, WANG Zhi-xing, LIU Wan-rong (School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China) Abstract: A mathematic model for the formation of the hollow fiber nanofiltration membrane by interfacial polymerization was established. The model described the process of interfacial polymerization controlled by both chemical reaction and diffusion control under non-steady-state conditions, which was applied into the process of diffusion control through the according simplification. At the same time, the experiment for the formation of membranes by interfacial polymerization reaction with piperazine-triethylamine as the aqueous phase, trimesol as organic monomer and toluene as the organic solvent in the organic phase respectively were made. The results show that after 10 s reaction, the thickness of composite membrane is