硅藻土基吸附剂的制备、表征及其染料吸附特性研究-材料学专业论文.docxVIP

摘要料吸附的影响。发现了哑甲基蓝(MB)染液在较高pH条件下，因水解或形成二聚体对 摘要 料吸附的影响。发现了哑甲基蓝(MB)染液在较高pH条件下，因水解或形成二聚体对 可见光的吸收强度随时间不断降低的现象。根据此现象，本文提出，pH值增大，硅 藻土或其它矿物吸附剂对MB脱色率增大的原因有两个：一是pH值越大，吸附剂表 面负电荷量越多，因此对阳离子染料MB的吸附增大：二是在高pHi-，MB自身水解 或形成二聚体导致脱色率增大。由于MB是表征吸附剂吸附性能最常用的染料之一， 该发现对于其它吸附剂的研究电具有参考价值。 4、修正了浓度比形式的准一级、准二级动力学速率方程。对动力学实验数据拟 合时，它们能更直观地表现吸附质浓度随时问的变化过程，而且在平衡吸附容量g。 未测定的情况下，它们均可根据动力学数据直接预测吸附剂的q。值：从而发展了准 一级、准二级动力学模型新的应用模式。 5、研究了热活化硅藻土与MGMD吸附剂的染料吸附等温线模型、动力学模型、 热力学参数，并提出了它们的染料吸附机理。结果表明，在Langrnuir、Freundlich 及Redlich—Peterson模型中，它们对染料的吸附等温线最符合Redlich—Peterson模型； 它们对染料的吸附过程则更符合准二级动力学模型；它们对染料的I吸附机理为：通 过静电引力、氢键、聆I兀作用及范德华力吸附染料分子，其中，静电引力和氢键吸附 起主要作用。 关键词：吸附剂，硅藻土，印染废水，染料，吸附等温线，动力学方程，热力学 II 浙江大学博士学位论文——AB涨CTABSTRACT 浙江大学博士学位论文——AB涨CT ABSTRACT A huge quantity of dye wastewater is discharged by textile，paper,plastic and leather industries every year．As many dyes are complex organic contained az0 and poly aromatic ring，which may cause people abnormal，CanCerOUS and mutagenic，the removal of dyes from these wastewaters is a very important subject．Lots of dyes are resistant to oxidation and degradation，SO adopting adsorbent to remove the dyes may be superior to other methods．11le activated carbon is a very effective adsorbent．but its high price limits its extensive use．The diatomite is abundant,porous and has high specific surface area, which make it hopeful to be one effective and low-cost adsorbent．However,the adsorption capability of raw diatomite still needs to be improved and the studies on its application and theory on dyes adsorption are still expected to be carried out further． In this paper,basing on the structure characteristics of diatomite，the preparation technique of adsorbent of M烈OHh—modified diatomite and polyacrylamide-modified diatomite ware developed witll the method of activated and combined the second composition,which improved the adsorption capability for dyes．Hence，the system study from preparation process，materials characterization and dye—adsorption property to the dye-adsorption theory and