光固化含硫环氧树脂纳米二氧化钛杂化材料的合成与性能研究-化学工艺专业论文.docxVIP

(／vIES)、2-笨基硫代乙硫醇(MEPS)、2，3．二巯基乙基硫代丙硫醇 (／vIES)、2-笨基硫代乙硫醇(MEPS)、2，3．二巯基乙基硫代丙硫醇 (BES)；然籍醴这三静巯醇和环氧氯丙烷为原料，通过直接法或问接 法合戒了三种含硫环氧树蒡蓦苯硫代乙基环氯嚣蒸硫醚(PTETE)、2,2’一 二蕊基二乙硫醚缩水甘澳醚型环氧越脂(DGEMES)穰2，3，二巯基乙 基硫代褥硫酵三乙硫醚缩水甘油醚型环氧树鹰(TGEBES)，它艉的折 光率分别为1．6178、 1．5661和1．5850，其环氧值分别为O。32、O，6l 和0．53mol／1009树脂。 利用有机硅／二：氧化钛纳米杂化材料(333与含硫环氧树脂TGEBES 组成涂覆材料，以六氟砷酸二苯基碘豁盐为该材料的阳离子引发剂，研 究了原料配比对光固化膜的各种性能的影响。研究结果表明：G33和 TGEBES的质量吾分含蹙各占50％的条件下，膜的综合性能最伉。 采耀透身孛电子显微电镜(TEM)对溶胶体系中缡米粒予静形虢遴行 了表锰。结巢表赞各静溶胶体系鲶缡米颗粒懿粒径在40～60nm范銎。 付立时红羚光谱(1R)对杂化材料翮含硫环氧撵￡旨进行了表征、核磁共 振谱图(1H。NMR)与袁效液捆色谯(HPLC)对含巯环氧树脂购结誊每 进行表征表明，三种含硫环氧树脂的纯度都在90％以上。扫描电子显微 镜表明纳米复合材料具有较好的相密性。 关键词：含硫环氧树腊，紫外光固化，膜，纳米杂化材料 A A Study on Synthesis and Performance of UV-curing Sulfur-Containing Epoxy Resins／Nanometer Ti02 Hybrid Material ABS，IIRAC，I- A technology called See／Through Hologram，which was used hi曲 refractive index materials to record hologram picture，has been considered a novel way in the field of holograph anti—counterfeit compared with the traditional hologram molding methods．The key to realize this technique is how to make the refractive index of those transparent materials as high as possible．So the reflective hologram not only was seen clearly,and the background picture but also was observed．The main work of this paper emphasized on how to get materials or resins that had high refractive index and could be cured by onium salt cationic photoinitiator via ultra violet radiation as well as studied the feasibility of their applying in the hologram anti—counterfeit field。So organic silane／nanometer Ti02 hybrid rnaterials alld sulfur-containing epoxy resins were synthesized and characterized，and the performance of their composite UV-curing films was researched． Four kinds of organic siloxane／nanometer Ti02 hybrid materials were synthesized by Sol—Gel process．The effect of three compounds by |“ s1羹gle s1羹gle g∞up coordination，five compounds by double group e沁lati跳黼d two compounds by bridge coordination on the size of nanometer- tr昌msparency and refractive inde