过氧化氢在化学修饰电极上的电化学行为研究-物理化学专业论文.docxVIP

I．1II I ．1II ．．1Vr ．．1 ．．1 ．．1 ．．3 ．．3 ．．5 ．．6 l 5 Chapter 1．Hydrogen peroxide sensor based Oil Prussian blue electrodeposited on (3-mercaptopmpyl)一trimethoxysilane polymer modified gold electrode ．．1 5 1．Introduction ．．1 5 2．Experimental 16 2．1 Reagents 16 2．2 Apparatus ．．1 6 2．3 Electrode preparation ．1 7 2．4 Electroehemical measurement 1 7 3．Results and discussion ．17 3．1 Cyclic voltammetry characterization ofself-assembly process 17 3．2 Electrochemical impedance spectroscopy characterization of self-assembly process 1 8 3．3 Characterization of PB film ．1 9 3．4 Electrochemical characteristics ofthe modified electrodes 21 3．5 Performance ofthe PB modified electrode for H202 detection ．22 3．6 Tolerance of potentially interfering substances ．23 4．Conclusions 。24 5．References ．24 ■ Chapter 2．Hydrogen peroxide SeI_kqor based on Prussian blue analogue doped with Cd(II) ～9 electrodeposited the self-assembled(3-mercaptopropyl)-trimethoxysilane gold electrode．．28 螺 1．Introduction ．．28 2．Experimental 29 2．1 Reagents 29 2．2 Apparatus ．29 2．3 Fabrication ofthe Modified Electrode ．．29 3．Results and Discussion 30 3．1 Electrochemical characteristics of self-assembly process 30 3．2 Characterization ofcadmium hexacyanoferrate(CdHCF)film 32 3．3 Electrochemical characteristics of the Au／MPS／C(1HCF modified electrode ．33 3．4 Performance of the modified electrode for H202 detection ．34 3．3 3．3 Optimization of experimental variables ．45 3．4 Amperometric performance of the macroporous silver membrane sensor to H202 47 4．Conclusions 48 5．References ．．48 Chapter 4．Preparation of ordered macroporous Prussian blue film electrode for hydrogen peroxide sensor application 52 1．Introduction 52 2．Experimental ．53 2．1 Reagents ．53 2．2 Apparatus ．．53 2．3 Synthesis of PS latex spheres ．．53 2．4 Fabrication ofthe ordered macroporous Prussian blue film electrode 54 3．Results and Discussion 55 3．1 Fabrication and characterization of ordered macroporous PB film ．55 3．2 Electrocatalyt