苯-烯烃-N-甲基吡咯烷酮汽液平衡的研究-高校化学工程学报.PDF

21 6 No.6 Vol.21 2007 12 Journal of Chemical Engineering of Chinese Universities Dec. 2007 1003-9015(2007)06-0914-05 --N- , , , ( , 300072) N- (NMP)C ~C 6 8 CE-2,-1--NMP-1--NMP-1- -NMP;WilsonNRTL UNIQUAC (0.008390.009260.00802)- -N- N- (NMP)(VLE) O642.42 A Study on Vapor-Liquid Equilibrium for Benzene+Alkene+N-Methyl-2-Prolindone Systems LI Ji-liang, ZENG Ai-wu, YUAN Xi-gang, YU Guo-cong (State Key Laboratory of Chemical Engineering, College of Chemical Engineering, Tianjin University, Tianjin 300072) Abstract: As an excellent solvent, N-methyl-2-prolindone (NMP) is widely used for refining benzene by extractive distillation. Since the necessary basic VLE data of benzene- alkenes-NMP systems are scarce, in this study, the vapor-liquid equilibrium data were determined at normal pressure for the three ternary systems of benzene-1-hexene-NMP, benzene-1-heptene-NMP and benzene-1-octene-NMP by using the CE-2 vapor-liquid equilibrium still. The data obtained were correlated respectively with Wilson, NRTL and UNIQUAC models. Using those models, the average deviations of vapor compositions between the experimental and predicted for those ternary systems are about 0.00839, 0.00926 and 0.00802, respectively. The results given complement the lack of the VLE data of benzene- alkenes-NMP systems and are significant for the refining the coking benzene by extractive distillation with NMP as solvent. Key words: N-methyl-2-prolindone (NMP); benzene; alkene; vapor-liquid equilibrium (VLE) 1