毕业论文-涤纶织物抗静电剂的制备和性能.docVIP

PAGE 本科毕业论文 （20 届） 涤纶织物抗静电剂的制备和性能 专业：高分子材料与工程 摘 要：本文采用对苯二甲酸二甲酯（DMT）、乙二醇(EG)、间苯二甲酸二甲酯5-磺酸钠(SIPM)以及不同分子量的聚乙二醇（PEG）合成一系列的亲水型聚醚酯，用于涤纶织物的抗静电处理。首先考察了反应条件（真空度、温度）对聚合反应的影响，其次考察了PEG分子量和用量以及SIPM的用量对整理剂抗静电性和耐洗性的影响，然后再考察了后整理条件，如工作液浓度、织物的浸渍时间、烘焙温度和烘焙时间对织物抗静电性能的影响，最后用红外光谱（IR）和示差扫描量热仪（DSC），凝胶渗透色谱仪GPC对聚合物进行了表征。实验结果表明酯交换的反应温度为190℃，缩聚反应温度为220℃，真空度为Δh4mmHg；用PEG-2500含量70%、DMT/SIPM=6/1.5所合成的聚醚酯具有良好的抗静电性能；工作液浓度为0.2%，织物浸渍时间为10分钟，烘焙温度为160℃，烘培时间为10min所处理过的织物抗静电性能最佳。 关键词：聚醚酯；抗静电整理剂；耐洗性 Preparation and Property of Polyester Fabric Antistatic Agent Abstract: In this paper, a series of hydrophilic poly(ether ester) derived from dimethyl terephthalate (DMT), ethylene glycol (EG), Dimethyl 5-sulfoisophthalate sodium salt hydrate(SIPM) and polyethylene glycol (PEG) with different molecule weight via ester exchange and polycondensation reaction. They are used as antistatic agent for polyester fabrics. The effects of the amount of PEG, SIPM and molecular weight of PEG on antistatic property of poly(ether ester) were investigated. Also the effects of finishing conditions such as concentration ,drying temperature on antistatic property and washing fastness were discussed Finally, the poly(ether ester) were character by infrared spectroscopy (IR) and differential scanning calorimetry (DSC), GPC. The results showed the poly(ether ester) based on 70%PEG-2500 had good antistatic property and washing fastness; The optimal finishing condition is as follows: The dipping time is 10 min, drying temperature is 160℃, drying time is 10 min and concentration of finishing agent is 0.2%. Key words: durability; Antistatic agent; polyester-ester PAGE 1 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc290740322 1.引言 PAGEREF _Toc290740322 \h 1 HYPERLINK \l _Toc290740323 2.实验部分 PAGEREF _Toc290740323 \h 2 HYPERLINK \l _Toc290740324 2.1 实验原料 PAGEREF _Toc290740324 \h 2 HYPERLINK \l _Toc290740325 2.2 实验装置 PAGEREF _Toc290740325 \h 2 HYPERLINK \l _Toc290740326 2.3 实验原理 3 HYPERLINK \l _Toc290740327 2.4 合成工艺 PAGEREF