毕业论文-涤纶织物亲水整理剂的合成和性能.docVIP

PAGE 本科毕业论文 （20 届） 涤纶织物亲水整理剂的合成和性能 专业：高分子材料与工程 摘 要：本文采用对苯二甲酸乙二醇酯（DMT）、乙二醇(EG)、间苯二甲酸二甲酯磺酸钠(SIPM)以及不同分子量聚乙二醇（PEG）,通过缩聚反应合成了一系列亲水型聚醚酯。考察了聚乙二醇的分子量、聚乙二醇用量对聚醚酯亲水性能的影响。同时也考察了整理涤纶织物时的整理条件如：工作液浓度、烘培温度对亲水性、耐洗性的影响。并以示差扫描量热计（DSC）、红外光谱（IR）和凝胶渗透摄谱仪（GPC）对聚醚酯结构进行了表征。结果表明聚醚酯中PEG2000含量为80%时具有良好的亲水性能和耐洗性；合适的后整理条件为：工作液浓度为0.3%、烘培温度为160℃；聚醚酯具有嵌段结构，PEG软段有明显结晶。 关键词：亲水整理剂；聚醚酯；耐洗性；亲水性 Synthesis and Property of Hydrophilic Finishing Agent for Polyester Fabric Abstract：In this paper, a series of hydrophilic poly(ether ester) derived from dimethyl terephthalate (DMT), ethylene glycol (EG), Dimethyl 5-sulfoisophthalate sodium salt hydrate(SIPM) and polyethylene glycol (PEG) with different molecule weight via ester exchange and polycondensation reaction. The effects of the amount of PEG and molecular weight of PEG on property of poly(ether ester) were investigated. Also the effects of finishing conditions such as concentration, drying temperature on hydrophilicity and washing fastness were studied when treating polyester fabrics. The poly(ether ester) were character by infrared spectroscopy (IR) and differential scanning calorimetry (DSC), GPC. The results showed the poly(ether ester) based on 80%PEG-2000 had good hydrophilicity and washing fastness; The optimal finishing condition is as follows: drying temperature is 160℃ and concentration of finishing agent is 0.3%. Key words： hydrophilic finishing agent; polyester-ester; washing fastness; hydrophilicity 目录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc290663889 1.引言 PAGEREF _Toc290663889 \h 1 HYPERLINK \l _Toc290663890 2.实验部分 2 HYPERLINK \l _Toc290663891 2.1 实验原料 2 HYPERLINK \l _Toc290663893 2.2 实验装置 PAGEREF _Toc290663893 \h 2 HYPERLINK \l _Toc290663894 2.3 实验原理 3 HYPERLINK \l _Toc290663895 2.4合成工艺 4 HYPERLINK \l _Toc290663896 2.5共聚物结构分析及性能检测 PAGEREF _Toc290663896 \h 4 HYPERLINK \l _Toc290663897 2.5.1聚合物结构与分子量分析 PAGEREF _Toc290663897 \h 4 HYPERLINK \l _Toc290663898 2.5.2涤纶织物的后整理工艺 PAGEREF _Toc290663898 \h 4 HYPERLINK \l _Toc2906638