碱性硫酸铝溶液吸收SO2试验研究-热力发电.PDF

第46 卷 第4 期 热 力 发 电 Vol.46 No.4 2017 年 4 月 THERMAL POWER GENERATION Apr. 2017 碱性硫酸铝溶液吸收SO 试验研究 2 温 高，马明辉 （内蒙古工业大学能源与动力工程学院，内蒙古 呼和浩特 010051） ［摘 要］试验研究了不同参数碱性硫酸铝溶液和硫酸铝溶液吸收SO2 的过程。结果表明：随着SO2 吸收量的增加，碱性硫酸铝溶液和硫酸铝溶液的pH 均呈下降趋势，但碱性硫酸铝溶液中 的活性Al3+对溶液的pH 下降具有较强的缓冲作用。同参数碱性硫酸铝溶液，无论SO2 吸 收量多少，SO2 吸收率均随着吸收液温度的升高而降低，且吸收液温度越高，降低程度越 大；当吸收液温度低于50 ℃，且每升碱性硫酸铝溶液SO2 吸收量不超过5 L 时，SO2 吸收 率最低也能达到95.18 %，吸收效果良好。 ［关 键 词］碱性硫酸铝；吸收；SO ；活性Al3+ ；pH ；温度 2 ［中图分类号］X773 ［文献标识码］A ［文章编号］1002-3364(2017)04-0033-06 ［DOI 编 号］10.3969/j.issn.1002-3364.2017.04.033 Experimental study on SO2 absorption in basic aluminum sulfate solution WEN Gao, MA Minghui (College of Energy and Power Engineering, Inner Mongolia University of Technology, Hohhot 010051, China) Abstract: The process of SO2 absorption by basic aluminum sulfate solution and aluminum sulfate solution with different parameters was experimentally studied. The results show that, with the increasing SO2 absorption, the pH value of both the basic aluminum sulfate solution and aluminum sulfate solution declined, But the active Al3+ in the basic aluminum sulfate solution has a strong buffering effect on the pH value’s drop.In the basic aluminum sulfate solution, SO2 reacted with the active Al3+ firstly, when the active Al3+ was exhausted, the gaseous SO2 would dissolve into the water. However, in the basic aluminum sulfate solution, due to the absence of active Al3+, the gaseous SO2 directly dissolved into t