纳米TiO2薄膜对痕量Cu的吸附研究-JournalofNortheastern.PDF

第32 卷第11期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol. 32, No. 11 2 0 1 1 年 11 月 Journal of Northeastern U ni ersity( Natural Science) N o . 2 0 1 1 TiO Cu( ) 2 1 1 2 李海军, 张 霞 , 孙海天 ( 1. , 110819; 2. , 110179) : - , , T iO . SEM XRD 2 , T iO 50 nm T iO . T iO , 2 2 2 T iO Cu( ) . pH Cu( ) 2 T iO , . T iO Cu( ) L, 2 2 . 10 mol/ L Cu( ) . : T iO ; Cu( ) ; ; 2 : O 652. 6 : A : 1005-3026( 20 11) 11- 1615-04 Study on Adsorption of Trace Cu( ) on TiO2 Nano-film 1 1 2 LI Hai-j un , ZHAN G Xia , S UN Hai-tian ( 1. School of Sciences, Northeastern Uni ersity, Shenyang 110819, China; 2. Northeast Yucai School, Shenyang 110 179, China. Corresponding author: ZHANG Xia, E-mail: xzhang @ mail. neu. edu. cn) Abstract: T iO nano-film w ith homogeneous surface w as prepared on the glass substrate by the 2 so-l gel method. The film w as characterized by SEM and XRD. The adsorption of trace Cu( ) w as carried out taking TiO nano-film as an adsorbent . The effects of pH alues, adsorption time, 2 initial concentrations of Cu ( ) and coexistent ions on the adsorption rates were studied systematically. The results show ed that the film is composed of anatase TiO nanoparticles w ith 2 the grain diameter about 50 nm. T he adsorption isotherm of Cu ( ) on T iO