光催化臭氧氧化处理水中难降解有机物-环境工程专业论文.docxVIP

光催化_臭氧氧化处理水中难降觯有机物Abstract 光催化_臭氧氧化处理水中难降觯有机物 Abstract A review of degradation of non-biodegradable organic compounds and tec|mique of photocatalysis combined with ozonation was firstly presented．And then the research aim was proposed．There are three parts in this paper：tI—acid(1-amino一8一naphthol一3，6-disulfonic acid)degradation by combined photocatalysis of UV irradiation and ozonation processes， proposed pathway ofH—acid degradation by the process and the treatment ofcoking wastewater by photocatalysis oxidation． (1)The experiment of H-acid degradation，by combined photocatalsis of UV irradiation and ozonation,shows that the synergistic effect exists on the decomposition of H—acid by combined photocatalsis ofUV irradiation and ozonation．The effects ofoperating parameters， i．e．the concentration of03，initial pH value，concen仃ation ofH-acid，concentration of sodium sulfate，were also investigated．It is found that the structure of H-acid is destroyed and its biodegradability is improved． (2)Intermediates ofH—aciddegradationby combinedphotocatalysisofUVirradiationand ozonafion were analyzed by some analytic technologies(UV-vis，IC，1H NMR,HPLC-MS)． Three intermediate products were identified：I-amino一5，7，8-lrihydroxynaphthalene一3，6一 disulfonate，8-hydroxy一1，2一naphthoquinone一3，6一disulfonate and 8-hydroxy-1,4一naphthoquinone 一3,6一disulfonate．The pathway ofH·acid degradation WaS discussed． (3)The degradation of coking wastewater exhausted from biochemical treatment by photocatalysis oxidation processes(03／TiOJUV and H20ffli03／UV)was studied and compared with photocatalysis，ozone and hydrogen peroxide only．For a reaction time of 90 minutes，the CODer of wastewater treated by the systems of photocatalysis oxidation, 03／Ti02／UV and H20fFi02AW，call be less than 80mg／L，which is far more efficient than Ti02／【Ⅳ、03 and H202．The effects of pH value and the concentrations of 03 and H202， which were controlling factors in 03／TiOz／UV and Hz02／Ti02／UV oxidation systems，were also studied．The ox