含碱金属有机物汽油抗爆剂的研究-应用化学专业论文.docxVIP

摘要硕士生：袁海欣(签名)盘i垒!i塾 摘要 硕士生：袁海欣(签名)盘i垒!i塾 指导老师：郭秋宝(签名) 童e丛：蔓 ．一 张耀君(签名) 郑远洋(签名) 摘要 在环保和节能的强烈推动下，实现汽油无铅化是车用燃料发展的必然趋势，但是 到目前为止，并没有一种十分理想的汽油抗爆剂来满足人们对高辛烷值汽油的需求。新 型高效、清洁的汽油抗爆剂的研制是当今～项急需解决的问题。 本文主要对十种碱金属羧酸盐用作汽油抗爆剂进行了全面系统的研究。将所合成 的十种碱金属羧酸盐分别通过助溶剂配制成一定浓度的浓缩液加入汽油中后，研究了它 们对汽油的腐蚀性、低温稳定性、诱导期、和胶质等性能的影响，着重考查了碱金属羧 酸盐对汽油抗爆性的改善效果，并对它们的加和效应、协同效应等作了进一步的研究。 实验结果表明，对于本研究中的十种碱金属羧酸盐，当碱金属在汽油中的质量百 分数为O．1％时，可使83，5号汽油的研究法辛烷值上升1～3个单位。而异辛酸钾和异辛 酸混合使用时，可使汽油的研究法辛烷值到达到90以上。碱金属羧酸盐作为汽油抗爆 剂加入汽油中后，汽油的低温稳定性良好，腐蚀性没有增加，诱导期符合国标要求。胶 质实验表明，这类化合物难以随汽油挥发，适用于电喷式发动机。 将碱金属羧酸盐用作汽油抗爆剂进行全面系统的研究在国内尚属首次。本实验中 所涉及到的十种碱金属羧酸盐的合成工艺都比较简单、原料来源丰富，成本相对较低， 其中异辛酸钾和异辛酸钠具有很好的开发和应用前景。 关键词：汽油抗爆剂碱金属羧酸盐辛烷值 论文类型：应用研究 Subject：Study Subject：Study 011 Gasoline Antiknock Additives of the Alkali Metal Organi。 Compounds Specialty：Applied Chemistry Name ：Yuan Haixin(signatur∞ j丝鱼堑丝垒i兰i! Instructor：Guo Qiubao(signature) 白∞凯{0∞ Zhang Zheng ABS Jl{AcI It is all inevitable trend for automobile engines to use unleaded clean fuels under the str- ong force of the environment protecting and energy saving．But up to now,there is no perfect gasoline additive tO meet the demand of the gasoline with high RON．It is urgent tO search and produce new,clean and high effective antiknock additives today． Ten kinds of alkali metal carboxylates have been studied systematically in this thesis．The The carboxylates were solved in proper solvents respectively to be made into concentrated solution．After the concentrated solution was added into gasoline，it was examined that the effect of the gasoline on corrosion，induction period，the gum-forming， stability under low temperature and SO on．The improvement effect of antiknock property of the gasoline containing the carboxylates was evaluated in detail．Especially their additive property and synergic effects witll other materials were studied further． The results show that the RON ofthe basic gasoline with 83．5#call be raised by l～3 units after added 0．1％(alkali metal mass percentage、of this antiknock additive into the gasoi