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Subject:Study
Subject:Study 011 Gasoline Antiknock Additives of the Alkali Metal Organi。
Compounds
Specialty:Applied Chemistry
Name :Yuan Haixin(signatur∞ j丝鱼堑丝垒i兰i!
Instructor:Guo Qiubao(signature) 白∞凯{0∞
Zhang Zheng
ABS Jl{AcI
It is all inevitable trend for automobile engines to use unleaded clean fuels under the str- ong force of the environment protecting and energy saving.But up to now,there is no perfect gasoline additive tO meet the demand of the gasoline with high RON.It is urgent tO search and produce new,clean and high effective antiknock additives today.
Ten kinds of alkali metal carboxylates have been studied systematically in this thesis.The The carboxylates were solved in proper solvents respectively to be made into concentrated solution.After the concentrated solution was added into gasoline,it was examined that the effect of the gasoline on corrosion,induction period,the gum-forming, stability under low temperature and SO on.The improvement effect of antiknock property of the gasoline containing the carboxylates was evaluated in detail.Especially their additive property and synergic effects witll other materials were studied further.
The results show that the RON ofthe basic gasoline with 83.5#call be raised by l~3 units after added 0.1%(alkali metal mass percentage、of this antiknock additive into the gasoine.When potassium isooetanate mixed with its precursor acid,the RON of the gasoline Can be raised to 90 or hi曲eL The other properties of the gasoline with these alkali metal
carboxylates,such as corrosion,stability at low temperature,have not to be affected and some properties have not to be affected seriously.The induction period meet the demand of the standard of our country.The gum-forming experiment indicates that some remainders in engine are difficult to be volatilized with gasoline.It means that they could be used only in
西安石油大学硕士学位论文the
西安石油大学硕士学位论文
the engines equipped with fuel injection system.
It is the first time in our country that t
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