含二氮杂萘酮结构聚醚砜酮耐热绝缘漆的-高分子材料专业论文.docxVIP

一bstractAbstract 一bstract Abstract P01yarylethers are well known high performance thermoplastics which generally exhibit high thermal and excellent impact resistance．They can also be used in insulating varnish and adhesive applications．But as varnishes，they have poor adhesion．In this dissertation，the copolymer PPESK was modified by adding active groups，such as hydroxy，amino and epoxy groups，to terminus or sides of macromolecules．The insulating varnishes were prepared by crosslinking PPESKs functionalized with other resins．The adhesion of varnishes was improved remarkably． 1．Epoxy-terminated poly(aryl ether sulfone ketone) (E—PPESK) was synthesized by the reaction of epichlorohydrin with PPESK oligomer prepared by nucleophilic substitution of 4，4’一dichloro—benzosulfone and 4，4’一dinuorobenzophenone with 4-(4-h，droxypheny)-2，3-phthalazin一1一one． 2。Amino·terminated poly(aryl ether sulfone ketone)was prepared by two steps． (1)PPESK oligomer reacted with P—Chloron“robenzene in the presence of potassium carbonate．(2)The copolymer made in former step was reduced by hydrazine in the presence of Pd-C． 3．Hydroxylized PPESK(PPESK—OH)was prepared by reaction of Natriumborhydrid，a high choice reduction agent，with PPESK． 4．The crosslinking reactions took place when modified PPESKs containing active group were cured with low molecular weight polyamide， polyurethane or epoxy resin．Insulating varnishes with excellent thermal， mechanical and electrical properties were made by this method． Key words：polyarylether，epoxy group，amino group，hydroxylize，synthesize， insulating varnish． 大连理工大掌硕士掌位’沦文刖 大连理工大掌硕士掌位’沦文 刖 吾 聚芳醚是一类耐高温热塑性特种工程塑料，可广泛应用于航空航天、 电子电气、核能、精密机械等领域，其具有代表性的品种是英国ICI公司 开发成功的半结晶性聚醚醚酮(PEEK)，Tg=143℃，Tm=335℃，可在240 ℃下长期使用。但PEEK在室温下只能溶于浓H2S04，只能采取高温(超 过其熔点的温度)合成，聚合后处理工艺复杂。且只能热成型加工，在涂 料、绝缘漆、分离膜等领域的应用受到限制。近年来，世界各大公司都投 巨资开发新品种，虽然产品的耐热性有一定程度的提高，但是均未能解决 溶解性差的问题。我国特种工程塑料的研究始于六十年代，先后列入“七 五”、“八五”、“九五”国家重点科技攻关计划。长春应用化学研究所于1985 年开发出一种可溶解的无定型聚芳醚酮(PEEK．C)，其Tg=23l℃，开创了 可溶性聚芳醚酮的发展史，但其耐热性明显降低，化学稳定性也欠