活性炭复合材料的制备及吸附水中有机物和砷的性能研究-市政工程专业论文.docx

内容摘要本文以活性炭、氧化铁为原料，制成多种氧化铁／活性炭复合吸附材料，通 内容摘要 本文以活性炭、氧化铁为原料，制成多种氧化铁／活性炭复合吸附材料，通 过对制备工艺、结构表征及其水中有机物和砷的吸附研究，获得了不同吸附剂 吸附水中有机物和砷的吸附性能数据，为控制和去除水中污染物提供理论依据。 把活性炭ACl分别用NaOH、HN03和氨水进行浸渍处理后，提高了活性炭 的表面含氧量并改变了其孔结构。发现活性炭ACl经过氧化处理后对水中有机 物的吸附显示不同的特征。用氧化后的活性炭与本实验自制的氧化铁合成 FeO／AC复合材料。通过物化性能测试表明氧化铁的存在改变了活性炭的表面结 构和表面物化性能。对吸附水中有机物的实验表明提高了甲醛吸附性能，降低 了甲酸和丙酮的吸附性能。 用草酸铁浸渍活性炭后，在温度为300℃、500℃和600℃氮气中还原活化一 小时制成FeO／AC复合材料。物化性能测定表明其比表面积比原活性炭增加。对 吸附水中有机物的实验表明在600℃下处理的活性炭提高了对甲酸和甲醛的吸 附，对丙酮的吸附性能改变不明显。在500℃下处理的活性炭仅对甲酸的吸附有 轻微的改善，而对甲醛和丙酮的吸附有下降的趋势。在300℃对三种有机物的吸 附与原活性炭相比都降低。 制备出氧化铁／活性炭复合吸附材料吸附去除水中砷，利用活性炭的载体作 用和氧化作用增强了铁与砷的亲和能力。研究证明复合吸附剂FeO／AC．H和活性 炭ACl对As(V)的吸附更符合Langmuir吸附模型，而复合吸附剂AC／Fe2(C204) 对As(V)的吸附比较符合Freundlich吸附模型。 关键词：活性炭，氧化铁，有机物，活性炭改性，液相吸附，复合吸附材料 AbstractIron Abstract Iron oxide／activated carbon(FeO／AC)composite adsorbent materials were prepared by activated carbon and iron oxide in this work． Adsorption characteristic data about different adsorbents removal of organic compounds and arsenic from aqueous solutions were gained through studying the preparation techniques，the characterization of pore structure and the adsorption performance．The obtained results possessed theoretic value for control ling contaminants in water． Apparent characters and physical chemistry performances of coal based carbon，wood based carbon，and specially made ferric oxide crystal were studied by the means of X．ray diffraction(XRD)，nitrogen adsorption，scan electronic microscope(SEM)，X．ray photoelectron spectroscopy(XPS)，and BET surface area．Adsorption dynamic character curves were acquired by adsorption experiments conducted in batch systems and fixed．bed adsorbers．which indicated the removal of formic acid，formaldehyde，acetone organic compounds from water by using the two kinds of activated carbon and the ferric oxide．These results provided theoretic basis for modifying the activated carbon materials and preparing the composite adsorbents． ￥eo|NC composite adsorbent materials were respectively compounded by coal．based activa