回收PET增强PP的制备与性能研究-材料工程专业论文.docxVIP

万方数据 万方数据 回收 PET 增强 PP 的制备与性能研究 摘 要 本文以 PP 为基体树脂，回收再利用的 PET（R-PET）为增强相，PP-g-GMA 或 POE-g-GMA 为增容剂，通过普通的熔融挤出和原位微纤化（熔融挤出-热拉伸- 淬冷）的方法制备得到了回收 PET 增强的 PP 复合材料（PP/R-PET）。通过采用扫 描电镜研究了复合材料的形态结构，通过傅里叶红外光谱（FTIR）研究了相容剂 的反应活性，利用万能拉伸仪机，摆锤冲击仪和热性能测试仪研究了复合材料的力 学性能和热性能。研究结果表明：增容剂（PP-g-GMA 和 POE-g-GMA）的加入， 能够显著改善 PP 基体与分散相 R-PET 的界面作用，提高两相的相容性，使热力学 不相容体系变成了热力学相容体系；而且随着增容剂（PP-g-GMA）含量的增加， PP/R-PET 共混物的拉伸强度，弯曲强度，拉伸模量和弯曲模量都显著增加，当增 容剂的含量超过 5%时，上述性能随之降低。研究同时发现，随着增容剂（PP-g- GMA）含量的增加，PP/R-PET 共混物的缺口冲击强度和热变形温度降低；当增容 剂（PP-g-GMA）含量为 5%时，PP/R-PET 共混物的综合性能达到最佳，且与纯 PET 增强的 PP 体系的性能接近，说明回收 R-PET 能够代替部分纯 PET，用于商业 化生产。当用 POE-g-GMA 取代 PP-g-GMA 做增容剂时，能在不明显降低 PP/R- PET 共聚物拉伸强度和弯曲强度的同时，显著提高 PP/R-PET 共聚物的缺口冲击强 度。进一步的研究发现，原位微纤化（熔融挤出-热拉伸-淬冷）加工方法能够显著 提高 PP/R-PET 共聚物的强度，模量和缺口冲击强度。 关键词：聚丙烯（PP），回收再利用的 PET（R-PET），PP-g-GMA，POE-g-GMA， 原位微纤化，性能 Fabrication of Recycled-PET Reinforced PP and its properties ABSTRACT In this study, Recycled PET reinforced PP was prepared by using PP as the matrix, during which recycled PET was used as the dispersed phase, and PP-g-GMA and POE-g- GMA as the compatibilizer, by using a normal twin-extrusion and in-situ microfibrillated technology (slit-extrusion-hot stretching-quenching). The morphology of the resultant composite was investigated by SEM(Scanning Electron Microscopy). Compatilizer effect was analysied by using FT-IR(Fourier Transform Infrared Spectrometer). The mechanical and thermal properties were measured by using mechnial and thermal tester. The results show: compatibilizer (PP-g-GMA and POE-g-GMA) can significantly improve the interface interaction between PP matrix and R-PET dispersion phase, improving the compatibility of the two components, from the originally thermodynamical incompatible system to thermodynamically compatible system. With the content increase of compatibilizer (PP-g-GMA), the properties of the tensile strength, flexural strength of PP/ R-PET blends, tensile modulus and flexural modulus increased significantly. When the content of the compatibilize