甲烷高压富氧燃烧层流扩散火焰的数值研究.docxVIP

DOI 10.11715/rskxjs. R201301006甲烷高压富氧燃烧层流扩散火焰的数值研究覃建果，魏小林，郭啸峰，李 腾，高佳佳(中国科学院力学研究所高温气体动力学国家重点实验室，北京 100190)摘 DOI 10.11715/rskxjs. R201301006 甲烷高压富氧燃烧层流扩散火焰的数值研究 覃建果，魏小林，郭啸峰，李 腾，高佳佳 (中国科学院力学研究所高温气体动力学国家重点实验室，北京 100190) 摘 要：对 0.1～4.0 MPa 范围内 CH4 富氧燃烧层流同轴射流扩散火焰进行了数值研究，研究对象包含 3 种工况：工 况 1 为 CH4/空气，工况 2 为 CH4/70%N2 和 30%O2，工况 3 为 CH4/70%CO2 和 30%O2．计算模型采用了基于 GRI 3.0 的骨干反应机理，该机理包含 26 种组分和 163 个反应，同时模型还考虑了 CH4、H2O、CO2、CO 的辐射换热损 失．结果表明，富氧燃烧使火焰温度升高、长度变短．工况 2 中 NO 排放指数与工况 1 相比增加了 70%，且随压力 的提高而增大，绝大部分 NO 是通过热力型 NO 途径形成．基元反应 H＋CO2 “ OH＋CO 使得工况 3 近燃烧器喷口 处的 CO 浓度大大增加．提高压力，火焰温度先升高后降低，火焰半径逐渐变小，火焰长度几乎不变． 关键词：甲烷；富氧燃烧；高压燃烧；NOx 文-章编号：1006-8740(2013)05-0425-09 中图分类号：TK16 文献标志码：A Numerical Study on Oxygen Enhanced Axisymmetric Laminar Methane Diffusion Flames at High Pressures Qin Jianguo，Wei Xiaolin，Guo Xiaofeng，Li Teng，Gao Jiajia (State Key Laboratory of High Temperature Gas Dynamics，Institute of Mechanics，Chinese Academy of Sciences， Beijing 100190，China) Abstract：Numerical study of three axisymmetric laminar co-flow diffusion flames at pressures between 0.1 — 4.0 MPa was conducted. One flame is a methane/air flame(Flame 1)，and the other two are methane/nitrogen-diluted oxygen flame(Flame 2)and methane/carbon dioxide -diluted oxygen flame(Flame 3)，the mass fraction of oxygen in the oxidizer of Flame 2 and Flame 3 are both 30%. Numerical model includes a skeletal mechanism derived from GRI- Mech 3.0 with 163 reaction steps and 26 species. An optically thin radiation sub-model was employed in the simula- tions to consider the thermal radiation absorption by species such as CH4，CO2，CO and H2O. As compared to Flame 1，the two oxygen-enhanced combustion flames are shorter and hotter. NO emission index in Flame 2 increases by 70% and increase monotonically with pressure. The majority of NO in Flame 2 is produced via the thermal route. The reaction step：H＋CO2 “ OH＋CO accounts for the high mole fraction of CO in Flame 3 near the fuel tube exit. As the pressure increases，flame tempe