活性炭吸附废水中CrⅥ及负载KOH催化制备生物柴油的研究-化学工艺专业论文.docxVIP

兰州大学化学化工学院2010届硕士学位论文Abstract 兰州大学化学化工学院2010届硕士学位论文 Abstract Because of the huge surface areas and chemical stability,the actived carbon is a kind of good adsorbents and catalysts．This thesis is devided into two parts to investigated the characteristic of the activcd carbon． The first part：Cr(VI)一containing wastewater is harmful to human being health and natural environment．So it is necessary to relrlove the Cr(VI)from the waste water． In this paper,the static test is carried out according to the capacity of adsorbents removing Cr(V1)．First，author is studied the adsorbability ofthe original actived carbon．When the pH ofwastewater is 3，the dosage ofaetived carbon is 0．5 g，the absorbing time is 3 h，the removal rate of Cr(V1)could be higher than 99．96％． When the nitric acid(7．6 tool／L)modification on the ash,pH ofwastewater is 4，the dosageof actived carbon is O．1 8岛the absorbing time is 3 llthe removal rate of Cr(VI) could be higher than 99．97％．Compared the original activcxi carbon，modified ash has higher adsorbability． The second part：Biodiesel was produced by tram—esterification of pricldyash seed oil catalyzed by solid base catalyst—KOH supported on active carbon．The conditiom to prepare biodiesel had been studied，such as catalyst，mole ratio of methanol to oil、dosage of catalyst and reaction time．The product Was analyzed by infrared spectroscopy and GC—MS．The molar ratio ofethanol to soybearl oil 10：1，the amount of catalyst was the quality of oil 3．0％(w)，reaction time 6 h，reaction temperature 75。C were the optimal conditions．Under the optimum conditions，we gained highly pure biodiesel，the yield could reach 87．3％． Keywords：activedcarbon，properties-modified，chrome·comaining Biodiesel， solid base catalyst，esterification II 原创性声明本人郑重声明：本人所呈交的学位论文，是在导师的指导下独立 原创性声明 本人郑重声明：本人所呈交的学位论文，是在导师的指导下独立 进行研究所取得的成果。学位论文中凡引用他人已经发表或未发 表的成果、数据、观点等，均己明确注明出处。除文中已经注明 引用的内容外，不包含任何其他个人或集体已经发表或撰写过的科研 成果。对本文的研究成果做出重要贡献的个人和集体，均己在文中以 明确方式标明。 本声明的法律责任由本人承担。 论文作者签名：生垂遘 El 期： 关于学位论文使用授权的声明本人在导师指导