环境友好型衣康酸共聚物的合成及性能研究-化学工艺专业论文.docxVIP

河北工 河北工业大学硕士学位论文 环境友 环境友好型衣康酸共聚物的合成及性能研究 万方数据 万方数据 万方数据 万方数据 ABSTRACT A novel environmentally friendly multifunctional scale and corrosion inhibitor containing carboxylic acid, sulphonic acid and phosphonic acid groups was synthesized from the monomers of itaconic acid (IA) , sodium allysulfonate (SAS) and sodium hypophosphite (SHP) by oxidation-reduction initiator system. The influences of reaction temperature, reaction time, NaH2PO2 amount and monomer composition on the scale inhibition efficiency were discussed. The optimum synthetic conditions were determined by orthogonal experiments. The structure of the copolymer was characterized by the means of infrared spectroscopy and elementary analysis. The performances of scale and corrosion inhibition, dispersion and biodegradability of the IA/SAS/SHP copolymer were studied. The results showed that the IA/SAS/SHP copolymer has good performances of scale and corrosion inhibition, dispersion performance on ferric oxide and biodegradability. When the concentration of IA/SAS/SHP copolymer was 20mg·L-1, the static scale inhibition rate on CaCO3 was 92.6 %. When the concentration of IA/SAS/SHP copolymer was 1.5mg·L-1, the dynamic scale inhibition rate on CaCO3 could reach above 90%. When the IA/SAS/SHP copolymer dosage was 28mg·L-1, the static scale inhibition efficiency on Ca3(PO4)2 could achieve 100%. the IA/SAS/SHP copolymer has good dispersion capacity for ferric oxide. When the concentration of IA/SAS/SHP copolymer was 30mg·L-1, the transmittance was only 65.7%. When the concentration of the IA/SAS/SHP copolymer was 60mg·L-1, the corrosion rate was 0.02823 mm·a-1 and the corrosion inhibition rate reaches above 90%. According to the analysis of Tafel polarization curves，the IA/SAS/SHP copolymer predominantly act as anodic inhibitor. In addition, 69.5% of the copolymer could be biodegraded within 28 days, which indicates that the copolymer is an environmentally friendly product. The synergistic scale inhibition performan