磺酸盐型Gemini表面活性剂的合成及作为精练剂的性能研究-纺织化学与染整工程专业论文.docxVIP

II II 中文摘要 磺酸盐型 Gemini 表面活性剂的合成及作为精练剂的性能研究 能很好的满足棉织物的后续加工要求。 探讨了 Gemini 表面活性剂及精练剂 G 对真丝织物的精练效果，并优化精练剂 G 的精练工艺。实验结果表明，精练剂 G 较 Gemini 表面活性剂具有更好的精练效果； 精练剂 G 用于丝织物精练的优化工艺为：精练剂 G 3g/L，精练温度 95℃，精练时间 40min。优化工艺下精练后丝织物的脱胶率、白度和毛效分别为 22.81%、75.5 及 19.5cm/30min。 关键词：磺酸盐型 Gemini 表面活性剂；合成；复配；精练剂；性能 作 者：曾 科 指导老师：赵建平 王祥荣 PAGE PAGE IV Study on the Synthesis of sulfonate Gemini Surfactant and performance as a scouring agent Abstract Study on the Synthesis of sulfonate Gemini Surfactant and performance as a scouring agent Abstract Comparing to ordinary surfactants molecules which have single hydrophobic chain and single hydrophilic group, Gemini surfactant is a novel surfactant which is made up of two amphiphilic molecules connected at the level of the head groups by a spacer group. Spacer group greatly reduces the tendency of separate from each molecule because of the charge repulsion between the ions head, thereby greatly enhancing the surface activity of Gemini surfactant. What makes Gemini surfactant has broad application prospects. This paper studied the synthesis route of sulfonate Gemini surfactant which is coupled by EDA. Using Ethylenediamine, 1,3-propanesultone and fatty chloride as main raw materials, three kinds of sulfonate Gemini surfactant N,N′-difattyacyl Ethylenediamine-sodium dipropane sulfonate（G-10、G-12、G-16）were synthesized by N-alkylation reaction and acylation reaction. The structures of the synthetic products were characterized by FT-IR and 1H NMR spectra. The properties of Gemini surfactants G-10、G-12、G-16 were tested, which includes surface tension、critical micelle concentration (cmc)、permeability、foaming performance、 washing performance、acid or alkali stability and resistance to hard water and so on. Experimental results show that, Gemini surfactant has a high surface activity, the average permeability, good foaming performance and washing performance, and excellent resistance to acid, alkali and hard water. With synth