环氧氯丙烷改性PAMAM的制备及其在染整中的应用-纺织化学与染整工程专业论文.docxVIP

Abstract This paper mainly studied the modification of PAMAM dendrimer and its application in fiber. This experiment used divergent method to synthesize the 2.0 generation PAMAM. And Epoxy chloropropane as raw materials to modify the 2.0 generation PAMAM dendrimer to be modified PAMAM dendrimer. The result showed that the materials ratio of PAMAM and Epoxy chloroproane was 1:12, and then reacted for 5h under the temperature of 55℃, then debase the temperature to 30℃ and reacted for 2h, the thickness of KOH was 50% and the yield was 70%. The cotton fabric was treated with 10g/L of the modified PAMAM and 40g/L of catalyst NaOH, baked at 130℃ for 75s, the results showed that the recovery angle increased by 17.5%, while the warp strength retention was over 90%, and the white content keeps over 85.1%, and the washing fastness was well. In order to improve the dye-ability of cotton fabric with reactive dyes, the cotton fabric was pretreated with modified PAMAM. The dyed modified PAMAM cotton fabric exhibited the similar K/S values and washing fastness and rubbing fastness in salt-free dyeing. Fourier transform infrared spectrophotometry indicated that the -OH group of the cotton fibers had reacted with the modified PAMAM. The results showed that fabric treated with 10g/L of modified PAMAM and 40g/L of NaOH, and reacted 5min under the temperature of 60℃. The dyed cotton fabric with reactive dyes in salt-free dyeing displayed better color strength, washing fastness and rubbing fastness. Key words: modification; dendrimer; crease-resist;salt-free dyeing; 目 录 第一章 绪 论 1 1.1 树枝状大分子概述 1 1.1.1 树状大分子的结构 2 组成 2 结构的完整性 2 几何对称性 2 分子内的空腔结构 2 端基官能团 3 相对分子质量的可控性 3 分子量的分散性 3 1.1.2 树枝状大分子的性能特点 3 流动性 3 溶解性 4 黏度 4 成膜性 4 多功能性 4 其他性质 4 1.2 树枝状大分子的制备方法 5 1.2.1 发散型合成法 5 1.2.2 收敛型合成法 5 1.2.3 发散收敛共用法 6 1.2.4 固相合成法 6 1.2.5 金属配位法 6 1.3 树枝状大分子的应用 6 1.3.1 在医学方面的应用 7 1.3.2 在催化剂方面的应用 7 1.3.3 在膜材料中的应用 8 1.3.4 在表面活性剂方面的应