环境温度对锌合金牺牲阳极材料性能的影响与合金化改性分析-材料加工工程专业论文.docxVIP

西安建筑 西安建筑科技大学硕士论文 西安建筑 西安建筑科技大学硕士论文 Effect ofEnvironmental Temperature on Performance of Zinc Alloys for Sacrificial Anode and Study of Modification of Alloys Specialty: Material Processing Engineering Name: Han Wei Instructor : Prof.Hua Jian -she Prof.Liu Chang-rui Abstract Zinc alloys are widely used in shipbuilding，oft:￥hore oil platform ，undersea pipel ines as cathodic protection ，because of their high current efficiency，l ight corrosion rate and long service life. Zinc anodes include Zn-Al，Zn -Sn，Zn-Al-Mn，Zn-A1-Cd，etc， and Zn-A1-Cd is the most wildly used. The performance of zinc alloy anode materials is easily atfected by ambient temperature，and the intergranular corrosion occurs under 70C in the 5ea，50 its application i5 limüed . Therefore，it is of significance to research th e law of ambient temperaωre intluence on the performancez inc of zi nc alloy sacrificial anode material for developing new excellent performance anode material Based on the saclificial anode prot巳ctive material s performance 陀quirements and the theory of alloys，Zn-A1，Zn-Cd ，Zn-In，Zn-RE，Zn-A1-Cd，Zn-RE 唰In alloys were prepared by adding alloying elements in zinc. By testing the electrochemical performance of the zinc alloy such as anode open circuit potential ，polarization curves ，corrosion rate and 50 on，and analyzing the microstructure ofthe zinc alloy，we got the regulation of A1， Cd，ln，RE influ ence on characteristics of Zinc anodes chemical behaviors under changed environmental temperaωre . The results show that: (I)With the am bient temperaωre increasi ng，the open circuit potenti al of Zn-Al 01 Zn-O.SAI-O. I Cd alloy was increased . The open ci rcuit potential of Zn O.SAI-O.ICd alloy changed from -1077.7mV at 20Cto -7J6.1mV at 70 C ，but the open potential of Zn-0.6Al anodic shifted from -1044.9mV at 20 C to -200mV at 70 C ， also the larger polarizability. The open circuit potential Zn-Cd alloys was reduced with increasing C