环氧大豆油的界面催化氧化合成研究-化学工艺专业论文.docxVIP

Subject : Interfacial Catalytic Oxidative Synthesis of Epoxy Soybean Oil Specialty : Chemical Technology (Signature) Name :Sha Wei Instructor : Yong-Jun He (Signature) ABSTRACT Epoxy Soybean Oil(ESO) as environmental,biologic degradative and steady plasticizer is an internationally recognized green plasticizing agent.ESO is a promising plasticizer for PVC,due to its good compatibility,light and heat stability, low volatile and migratory.Meanwhile it also has non-toxic and good stability for the food and pharmaceutical packaging materials. At present,ESO is produced by a non-solvent route with hydrogen peroxide as oxidant and formic acid or acetic acid as catalyst.This route has disadvantages such as the low reaction stability and epoxy value of products, deep color of products, equipment corrosion and environmental pollution. Here，we report a new interfacial catalytic synthesis method for preparing ESO by using hydrogen peroxide as an oxidant and solid catalyst. This route has advantages such as the simple reprocessing, just washing can separate two-phase. The key of this route is preparation of a effective, cheap and steady catalyst. Therefore, this paper aims to prepare a new solid catalyst for synthesizing ESO, study the catalytic effect of different catalysts. The effect of the reaction conditions on the epoxy value was investigated. The interfacial catalytic reaction mechanism was discussed. First, the catalyst of MoO3 /French chalk was prepared by impregnating.The effect of the factors on catalytic activity and stability was investigated according to the epoxy value of products, including the Mo capacity, calcination temperature, calcination time.The reason was discussed by structure characterization.The best catalyst preparation condition was obtained: the Mo capacity is 20%, calcination temperature is 400℃ and calcination time is 4h. The catalyst of MoO3/French chalk was used to synthesize ESO. The effect of the reaction temperature, the vo