甲基-1丙二醇水溶液密度和粘度的测定及关联-高校化学工程学报.PDF

20 4 No.4 Vol.20 2006 8 Journal of Chemical Engineering of Chinese Universities Aug. 2006 1003-9015(2006)04-0638-05 2--1,3- , , , , ( , 450002) 2--1,3-(MPO)MPO+298.15~367.15K MPO MPO MPO+ 70% V E ∆η V E ∆η , Grunberg-Nissan MPO- ∆G ij 2--1,3- ( MPO) O623.413 A Densities and Viscosities of 2-Methyl-1,3-Propylene Glycol + H O 2 System at Different Temperatures and Different Compositions LI Hui-ping, WANG Hong-mei, JIANG Deng-gao, LIU Quan, WU Kun (Research Institute of Fine Organic Synthesis, College of Chemical Engineering, Zhengzhou University, Zhengzhou 450002, China ) Abstract: Under the atmospheric pressure and by using the Ostwald-Sprengel-type pycnometer and the Ubbelohde capillary viscometer, the densities and viscosities of the binary system, 2-methyl-1,3-propylene glycol (MPO) + H2O, were measured at the temperature range of 298.15~367.15K and over the whole MPO molar fraction range. The experimental results show that under a given composition, both the densities and viscosities decrease with increasing temperature, and the densities decrease linearly while the viscosities decrease exponentially with the increase of the temperature. Under a given temperature, the density changes with changing MPO concentration and there is a maximum value of density at MPO concentration of about 70%. The experimental data of densities and viscosities were also used to determine the excess molar volumes VE and