正丁醛自缩合合成辛烯醛反应催化剂研究进展-NSFC.PDF

http :/ / www ． hxtb ． org 20 13 76 4 ·3 13 · 化学通报 年第 卷第 期 正丁醛自缩合合成辛烯醛反应催化剂研究进展 陈翠娜 吴丽丽 安华良 赵新强* 王延吉 ( 300 130 ) 河北工业大学化工学院绿色化工与高效节能河北省重点实验室 天津 、 摘 要 针对目前工业生产中正丁醛自缩合合成辛烯醛使用液体碱催化剂所带来的环境污染严重 生 、 ， ， 产成本高 产物选择性低等缺点 着重分析了研究开发中的各种固体碱催化剂的优缺点 并指出了提高催化 。 ， 。 稳定性是其研究方向 此外 还对酸碱双功能固体作为该反应催化剂进行了展望 关键词 正丁醛 羟醛缩合辛烯醛 固体碱 酸碱双功能催化剂 Progress on the Catalyst for the Synthesis of 2 -Ethyl-2 -hexenal via n -Butyraldehyde Self-condensation * Chen Cuina ，Wu Lili ，An Hualiang ，Zhao Xinqiang ，Wang Yanji (Hebei Provincial Key Lab of Green Chemical Technology ＆ High Efficient Energy Saving ， School of Chemical Engineering ＆ Technology ，Hebei University of Technology ，Tianjin 300 130 ) Abstract The catalysts for the synthesis of 2 -ethyl-2 -hexenal via n-butyraldehyde self-condensation were reviewed ． There are several disadvantages such as serious environmental pollution ，high production cost and low desired product selectivity in industrial technology using liquid alkali catalyst ． Based on the analysis for the advantages and disadvantages of solid bases catalysts in R＆D it is pointed out that the improvement of their catalytic stability will be the further research direction ． Additionally acid-base bifunctionalized solid will be expected as the catalyst