镁二次电池负极材料研究-材料加工工程专业毕业论文.docxVIP

II II 沉积形貌的粗糙度逐渐增加。比较而言，三种合金材料中 AZ31 合金 表现出了相对理想的电化学性能。 本文还进一步研究了镁钕合金作为镁二次电池负极材料的性能， 发现镁在其表面可以进行稳定的溶解-沉积循环，并且镁的表面沉积形 貌致密、规整。三种合金都具有良好的溶解-沉积循环特性，虽然起始 循环的稳定性较差，但随后能很快进入稳定状态，过电位也随之下降。 此外，随着合金中钕含量的增加，电极的过电位逐渐升高，说明钕元 素的加入增加了电极极化。 关键词：镁二次电池，镁合金，负极材料 PAGE PAGE IV Research on Anode Materials of Rechargeable Magnesium Batteries ABSTRACT Magnesium has similar properties with lithium in many respects, such as ionic radius and chemical properties. Rechargeable magnesium battery is a new kind of green battery which is promising for the application in electric vehicles. In addition, magnesium is relatively inexpensive, environmentally friendly, safe to handle and abundant in resources, so it is absorbing more and more attention from people. At present, research on rechargeable magnesium battery is under elementary development, and focused on cathode materials and electrolyte systems. However, there are few researches about anode materials, and usually use pure Mg as anode materials. To control the dendrite growth and improve the long-term cyclic performance, magnesium alloys were employed as anode materials. The electrochemical properties and surface morphology of AZ31 alloy and commercial pure Mg as anode materials in Mg (AlCl2EtBu)2/THF electrolyte were studied using cyclic voltammetric, constant current charge/discharge and scanning electron microscopy. The results showed that, as anode material of rechargeable magnesium battery, the over-potential of magnesium dissolution-deposition on AZ31 alloy was a little higher than that on commercial pure Mg, and the coulombic efficiency during the initial cycles was lower than that of pure Mg, but the coulombic efficiency of AZ31 remained stable in the long-term cycling compared to pure magnesium. Furthermore, AZ31 alloy effectively restrained the growth of dendrite on the surface of anode material and improved the cyclic performance of batteries. Comparing the cyclic performance and surface morphology of AZ31, AZ61 and AZ