聚酰胺酰亚胺涂层添加润滑剂对其摩擦性能的影响.pdf

第47 卷 第2 期 表面技术 2018 年2 月 SURFACE TECHNOLOGY ·123 · 聚酰胺酰亚胺涂层添加润滑剂对其摩擦性能的影响 杨帆，齐育红，崔立英，冯建东，李莉，纪冰楠，张占平 （大连海事大学 材料科学与工程系，辽宁 大连 116026） 摘 要：目的研究固体润滑剂对聚酰胺酰亚胺（PAI ）涂层摩擦磨损性能的影响。方法 由偏苯三酸酐（TMA ） 和4,4-二苯甲烷二异氰酸酯（MDI ）合成并添加二硫化钼、二硫化钨、石墨制备自润滑PAI 涂层，并对其用 HSR-2M 型高速往复摩擦试验机进行磨损实验。结合ATR-FTIR 、TA-TG 热重、磨痕形貌等表征手段，对自 润滑 PAI 涂层摩擦性能进行表征，探究了固体润滑剂的种类与含量对聚酰胺酰亚胺涂层摩擦性能的影响。 结果 载荷与PAI 涂层的摩擦系数呈反比例关系，当MoS2 含量达到30%时，PAI 涂层的摩擦系数降至0.1744。 添加固体润滑剂后，PAI 涂层的摩擦系数减小，磨痕宽度变窄，磨痕变浅，表面粗糙度相对较低。结论 具 备最佳摩擦性能的涂层添加了30%MoS ，添加10%石墨的涂层次之，添加10%WS 的涂层较好。添加固体 2 2 润滑剂可明显提高PAI 涂层的摩擦磨损性能，增加其使用时长。 关键词：聚酰胺酰亚胺；摩擦磨损性能；自润滑涂层；润滑剂；载荷；磨痕形貌 中图分类号：TG174.4 ；TH117 文献标识码：A 文章编号：1001-3660(2018)02-0123-07 DOI ：10.16490/j.cnki.issn.1001-3660.2018.02.020 Effects of Lubricant on Fricational Properties of Polyamide-imide Coatings YANG Fan, QI Yu-hong, CUI Li-ying, FENG Jian-dong, LI Li, JI Bing-nan, ZHANG Zhan-ping (Department of Materials Science and Engineering, Dalian Maritime University, Dalian 116026, China) ABSTRACT: The work aims to study the effects of solid lubricant on friction and wear properties of polyamide imide (PAI) coatings. Self-lubricating PAI coatings were prepared by synthesizing trimellitic anhydride (TMA) and 4,4-diphenylmethane diisocyanate (MDI), and adding molybdenum disulfide, tungsten disulfide and graphite. Wear test was performed to the coatings with HSR-2M high-speed reciprocating friction testing machine. Friction properties of the self-lubricating PAI coatings were characterized by means of ATR-FTIR, TA-TG thermogravimetry and wear scar morphology. The effects of types and content of solid lu