镁基块体非晶合金的制备及性能研究-材料加工工程专业毕业论文.docxVIP

兰州理工大学硕士学位论丈 兰州理工大学硕士学位论丈 Abstract Abstract The amorphous ribbons of M965Cu2sYl0，MgToCu20Y10，MgTsCulsYl0 and Mgs0Cul0Y10 alloys were prepared by vacuum melt spinning method and 2mm diameter rods of M965Cuz5．xNkYto(X=1，2，3)and M960．xAlxCu30Y10(x=0．3，0．9，2．1)were also prepared by vacuum copper mold casting method in this paper．The structure，glass forming ability (GFA)and crystallization process while heating were studied by differential scanning calorimeter analysis(DSCB3TA)and X-ray diffraction analysis(Ⅺ嘞respectively． The values of％、瓦、乃、r,e and△瓦for amorphous ribbons，which are the parameters to describe the glass forming ability for bulk metallic glasses and are expressed only by temperature，were deduced from DSC curves and the ratio of the crystallization heat and melting heat was presented as a new parameter-reduced glass transition enthalpy．DSC quantification analysis showed that this flew parameter and old parameters gave consistent results when described the glass forming ability of Mgz0．xCulo+xYlo amorphous ribbons． It is identified that the width of super cooled regionATx of M965Cu25。xNixYm(x=l，2，3) will be enlarged、Ⅳitll little Ni addition and the width will reach as much as 43．30K when x=1．The glass forming ability will be increased with larger Ni addition and will reach up to O．5892 when x=3．It indicates that a proper amount of Ni substituting Cu in the alloy will increase the glass forming ability but decrease the thermal stability．The glass forming ability of Mgso_xAlxCus0Yi0(x=O．3，0．9，2．1)bulk amorphous alloy will decrease while AI substituting Mg and the thermal stability and GFA ofthe amorphous alloy decreased at the same time． Crystallization process ofM965Cu25．xNixYm(x=1，2，3)alloy was studied when heating by use of Kissinger equation．The results show that the dynamics effect exists in the glass transformation and crystallization pr