棉用自交联型耐久阻燃剂的合成及性能-纺织化学与染整工程专业毕业论文.docxVIP

AbstractSynthesis Abstract Synthesis and application of new Durable flame—retardant ou Cellulose Fiber The flame—retardant agents used for cellulose material are usually composed of organic compound and inorganic compound，inorganic compound is widely utilized and accounts for 60 percent of total agents due to its effective，accessible and cheap property．but its non·durable property and absorption limits its further use in the textile field．So far， THPS，THPOH·NH3(based on THPC)and Pyrovatex CP(produced by ciba company)have dominated the world market．the former is gradually abandoned because cancer-inducing materials and toxic gases are formed during the course of processing，the latter has a N·hydroxymethyl constructure and will consequently release formaldehyde，which contradicts to the environmental protection law．in this respect，the International Textile Ecology Study and Detection Association has established Oeko—Texl00 standard to limit the maximum release offree Formaldehyde China also publicized compulsive standard GB 1 840 1 aiming at solving such situation．So the development of green flame·retardant faces emergent situation． Based on numerous references，we developed a lleW P-containing flame retardant agent，after careful and endless experiment，finally we find out the influence of reaction temperature，the pH value，and the molar ratio on the yield of product．Meanwhile，we utilized our product directly onto cellulose fiber without further purification，during the finishing process，the factors that influence the flame—rctardant property including the content of the flame retardant agent，baking temperature and time，pH value arc investigated．Thus a practical process and formula comes into being．We 2 Abstractprocess Abstract process the fiber according to this formula and compare it with CFR一20 1， and it shows the following results： Compared with CFR一20 1，the new developed agent possesses excellent durable flame retarding property：its indexes of after flame time， af