自组装催化剂对劣质催柴加氢性能的研究.docVIP

纳米自组装催化剂对劣质催柴加氢性能的研究 李思洋⑴，王鼎聪⑵，赵德智W (1、辽宁石油化工人学石油化工学院，辽宁抚顺113001) (2、中国石化抚顺石油化工研究院，辽宁抚顺113001) ：采用二次纳米白组装方法制备堆积密度低、金属负载量高的大孔催化剂。X射线衍射、圧汞和氮吸 附等结果表明，共孔径大部分集屮在30nm~100nm,占催化剂孔径分布的44.83%。以劣质催化裂化柴油为原 料，在微型反应器中评价纳米口组装催化剂对催化裂化柴油的脱硫、脱氮、芳烧饱和的活性，并用现冇工 业催化剂为参比剂(F2)做对比。结果表明，纳米自组装催化剂(FA9)加氢精制劣质催化裂化柴油的最高 脱硫、脱氮率达99%,而且有较高的芳绘饱和活性。在反应100h后，催化剂FA9仍然具有较高的活性，其 脱硫率、脱氮率、芳绘饱和率分别为95.4%、97.50%、62.41%：而参比剂F2脱硫率、脱氮率、芳绘饱和 率分别为94.4%、为98.20%、63.85%。计算结果表明，催化剂FA9的单位体积活性金属的硫脱除率是参比 剂F2的1. 75倍、氮脱除率是参比剂F2的1. 72倍、脱芳饱和率是参比剂F2的1. 70倍。 关键词：纳米口组装催化剂；催化裂化柴油；脱硫；脱氮；芳烧饱和 The research nano self-assembly catalyst for hydrodesulfurization of FCC diesel Li Si-yang,Ding Wei,Song guan-long,ZHAO De- zhi⑴：Wang Ding-cong[21 (1、 Liaoning Shihua University, Fushun Liaoning 113001, P.R.China； 2. Fushun ResearchInstitute of Petroleum and Petrochemicals , Fushun Liaoning 113001, P . R? China) Abstract* Adopting secondary nano self-assembly method to prepare macroporous catalyst with small stacking density and high metal loading,the distribution of pore volume centralized from 30 to 100 nni,which accounts for 36.13% of the catalyst total pore size distribution.Thc evaluation of nano self-assembly catalyst and desulfurization, denitrification and aromatic saturation activity is performed in the micro reactor with inferior catalytic cracking diesel oil as raw material, and with reference agent as a contrast.The results show that inferior catalytic cracking diesel oil refining by using hydrogenation techniques with nano self-assembly catalyst (FA9) has high dcsulfurization,dcnit「ificd(ion and aromatic saturation activity,and the highest removal rate reached 99%.After 100 h reaction,catalyst FA9 still has high activity, the desulfurization rate of nano self-assembly catalyst was 95.4%, the denitrification rate was 97.50% and the aromatics saturation rate was 62.41% ;while the desulfurization rate of F2 catalyst was 94.4%, the denitrification rate was 98.2% and the aromatics saturation rate was 63.85% .The desulfurization rate