煤化工工业废水熄焦对焦炭影响化学工程专业毕业论文.docxVIP

摘 摘 要 I I 摘 要 旭阳煤化工集团邢台园区是集炼焦、煤焦油深加工、粗苯加氢精制、焦炉煤气 制甲醇等一体的综合性工业基地。园区内焦化公司采用湿法熄焦，即将熄焦水直接 喷淋在红焦上熄焦的一种方法。湿法熄焦需水量大，在设计上熄焦水主要采用处理 后的蒸氨废水同时补充部分清水。 现我国有 16 个省(区、市)人均水资源量(不包括过境水)低于严重缺水线，甚至河 北等 6 个省、区人均水资源量低于 500 立方米。邢台位于河北南部，贫乏的水资源 制约着公司的发展。 园区内焦化公司年产干全焦 350 万吨，现公司的雨水、生活污水、工艺上产生 的蒸氨废水、酚氰废水等处理后都用于熄焦，但仍然无法满足用水需求，需要补充 大量新水。2009 年集团向焦化下游产业发展，陆续建立煤焦油深加工、粗苯加氢精 制和焦炉煤气制甲醇等项目。将煤化工产生的废水处理后用于熄焦，现发现焦炭指 标产生一定波动。通过实验检测发现煤化工废水对焦炭灰分、硫分、热态反应性和 反应后强度影响较大。采用稀释法（将煤化工废水用普通熄焦水稀释至不同浓度 100%、50%、25%、10%、5%、2.5%、1%、0.5%）分析废水对焦炭指标的影响，分 别找到煤焦油深加工、粗苯加氢精制和焦炉煤气制甲醇影响焦炭指标的拐点为 1%、 0.5%、2.5%。既可稳定焦炭的质量，又提高水资源的利用率。 关键词 煤化工废水；灰分；硫分；热态反应性；反应后强度；稀释法；水资源利 用率 河北科技大 河北科技大学硕士学位论文 II II Abstract Xingtai industrial park of Xuyang Coal Chemical Group is an integrated industrial base which has coke, coal tar, crude benzol hydro-refining, coke oven gas to methanol. Coking Company uses coke wet quenching method which is upcoming spray water directly on the red coke quenching. The coke quenching water need plenty of water which is treated ammonia wastewater and some clear water. Now severe water shortage exists in 16 provinces (autonomous regions and municipalities) in China and the water resources per capita(excluding transit water) is below the line of severe water shortages, and in Hebei and other six provinces and autonomous regions water resources per capita is even less than 500 cubic meters. Xingtai is in the southern of Hebei, and poor water resources restricts the development of our company. Our company products 350 million tons of dry coke every year and our company’s rainwater, sewage, process wastewater generated by steaming Ammonia, phenol cyanide wastewater are used for coke quenching after treatment, but it still can not meet the water needs.So we need add a lot of new water. In 2009, our company developed to the downstream industries of coking.We have established successively the deep processing of tar, crude benzene hydrogenation and gas methanol and so on. Now we use coal chemical wastewater for coke quenc