卤代磺酸及氨基磺酸树脂催化剂的制备及应用研究-有机化学专业毕业论文.docxVIP

ABSTRACTMacroporous ABSTRACT Macroporous sulfonic resins are extensively used as catalysts in various chemical reactions．In general，they are sulfonated from the macroporous poly(styrene—CO—divinylbenzene)using concentrated sulfuric acid as the sulfonating agent，which means that the structure of them is mainly composed of two parts，namely the polystyrene carder and acid active sites—S03H．Therefore，functional modification of sulfonic resiIls should be revolved mainly around the polystyrene carrier and active sites． In this study,the precursor sulfonic resin was halogenated，and a series of halogenated macroporous sulfonic resins was synthesized．These modified resins possessed a larger contact angle of water droplet than the precursor and a significantly improved thermal stability．Furthermore，the base sites were introduced into benzene tings of the resin，and a series of aminosulfonic resins containing N-S03H，N-Alkyl—S03H， and -NH2-S03H type structure were synthesized，respectively．The effect of amines and sulfonic acids distribution on the catalytic activity of aminosulfonic resins had been analyzed experimentally,and the proton transfer in catalytic process Was also studied． 1．A series of halogenated macroporous sulfonic resins A_1 5．Cl， A-1 5_Br and A一1 5一1 were synthesized from the precursor Amberlyst 1 5 by a typical halogenation reaction．Halogenation reaction not only has III 万方数据 almost almost no effect on pore structure but also has contributed to a larger contact angle of water droplet than the precursor and a significantly improved thermal stability． 2．The catalytic activity of the halogenated macroporous sulfonic resins was evaluated by the Biginelli reaction and follows the order： A-15一BrA一15一C1≈A一15-IAmberlyst 15．Their catalytic activity was much improved because of the positive inductive effect and hydrophobicity of the halogenated groups，among which the resin A．1 5—Br-4 containing 3 1．27％bromine exhibited the best catalytic activity and excellent