离子液体在纤维素预处理过程中的应用研究-化学工程与技术专业毕业论文.docxVIP

北京化工大学硕士学位论文采用的水解反应的条件是：100℃，N一甲基吡咯烷酮硫酸氢盐 北京化工大学硕士学位论文 采用的水解反应的条件是：100℃，N一甲基吡咯烷酮硫酸氢盐 ([Hnmp]HS04)的用量为lg，加水量为lg，金属盐MnCl2的用量为 O．159。 实验研究发现，提高温度能够提高纤维素的水解速率，得到较高 的总还原糖产率，明显缩短反应时间，同时，还原糖的降解速率也高； 酸性离子液体用量增加，纤维素的水解速率和还原糖的产率并不是按 比例增加，过多的离子液体用量会使还原糖的降解速率加快，降低还 原糖的产率；反应体系中存在过多的水会抑制纤维素的水解，降低还 原糖产率和纤维素的水解速率；纤维素的聚合度大，会使纤维素水解 的速率降低，同时也会使最大还原糖产率产率降低。 关键词：离子液体，纤维素，水解，还原糖产率 万方数据 ABSTRACTAPPLIED ABSTRACT APPLIED RESEARCH OF IONIC LIQUIDS IN CELLULOSE PRETREATMENT PROCESS ABSTRACT With the continuous development of human society,the demand for energy is more and more strong，at present，the fossil energy accounted for a large proportion in the energy structure in the world，however,a large number of unrenewable fossil fuels were exploited and used， including petroleum，coal etc．The world is facing energy crisis and serious environmental pollution problems． Cellulose is environment—friendly energy material，it has no pollution to the environment：The key step is the conversion of cellulose to sugars in the process for using the cellulose．Ionic liquid can play an important role in the pretreatment of cellulose．． There is the synthesis of five kinds of ionic liquids in this paper： 1．allyl一3．methylimidazole chloride salt([Amim]C1)，N—methylimidazole hydrogen sulfate([Hmim]HS04)，N—methylimidazole dihydric phosphate([Hmim]H2P04)， N—methyl， pyrrolidone hydrosulfate ([Hnmp]HS04)， N—methyl Pyrrolidone dihydrogen phosphate ([Hnmp]H2P04)．We use 1-allyl一3一methylimidazole chloride salt to dissolve cellulose，then we can obtain regenerated cellulose after Ill 万方数据 万方数据 万方数据 北京化工大学硕士学位论文centrifugal 北京化工大学硕士学位论文 centrifugal and washing process by adding anti—solvent，such as distilled water．We can mixed cellulose and acidic ionic liquids，acidic ionic liquid can catalyze the hydrolysis of cellulose to obtain reducing sugar．The total reducing sugar are analyzed by the method of 3,5一dinitrosalicylic acid． We explore the influence of five factors on the yield of reducing sugar, including reaction