锂离子电池高容量富锂层状正极材料制备与包覆改性研究-材料学专业毕业论文.docxVIP

的稳定性，抑制了 SEI 膜阻抗和电荷转移阻抗在充放电循环过程中的快速增长， FePO4 为非晶态的电化学活性材料，有利于锂离子扩散，同时提高主体材料的容 量。LiF 包覆层在电解液中可以保持稳定，有效阻止了电解液中 HF 对主体材料 的侵蚀，改善其循环性能。Li3PO4 包覆层作为固态电解质，可以在保护电极的同 时促进锂离子在电极界面的扩散从而改善了材料的电化学性能。 关键词： 锂离子电池 富锂正极材料 前驱体 包覆 电化学性能 ABSTRACT The developments of electric vehicles, smart grid and large-scale energy storage have put forward high demands on lithium ion batteries (LIBs) with high energy density and power density. At present, developing new cathode materials with high voltage and capacity has become the critical factor for further increase in energy density of LIBs. Li-rich layered cathode materials have been recognized as an ideal candidate of cathode material for the next generation LIBs due to its high capacity, low cost, high safety and environment friendly. However, there are still some key issues to be addressed before application, such as large initial irreversible capacity, poor rate performance, and capacity fading. In this work, Li-rich layer cathode materials have been synthesized via co-precipitation followed by calcination, and the preparation of precursor, optimization of synthesis conditions, and surface coating modification are investigated systematically. Li-rich cathode Li1.2Mn0.6Ni0.2O2 has been pilot synthesized by co-precipitation followed by calcination. The influences of NH3·H2O concentration and stirring speed on the precursor (Ni0.25Mn0.75)CO3 are studied, and the electrochemical performance of Li1.2Mn0.6Ni0.2O2 is investigated under 25 and 55 oC, respectively. The result shows that the high concentration leads to the actual composition deviating from the designed value. And the fine particles are easily formed at low concentration and result in low tap density. The final product is spherical particle with average size of 8.68 μm and tap density of 2.06 g/cm3. The initial discharge capacity is 239.9 and 298.9mAh/g under 25 and 55oC, respectively, and shows excellent cycle stability. Li-rich cathode Li1.2Mn0.54Ni0.13Co0.13O2 has been s