三元接枝改性sbs胶粘剂的制备及性能研究-材料学专业论文.docxVIP

Su两ect Su两ect ：Study on the Synthesis and Properties of Ternary Grafted SBS Adhesive Specialty：Material Science Name ；Wu Jianning (Signature)幽配妇d巡 V Instructor：Cai Huiwu (Signature)么：碰烂竺： ABSTRACT Styrene-butadiene-stbaene(SBS)is a non-polarity material，for its structure and surface energy are similar to polyolefin，it call bond with the hard bonded materials of non-polari％ high crystallization and low surface energy,but the bonding capability to some polarity material is pooL In order to enhance the adhesive performance of SBS，this paper increases the polarity ofSBS adhesive through grafting modification monomer． The paper discuss the main factors of impacting the bonding performance in preparing the ternary grafting SBS adhesive by single factor means，such as solvents，modified monomer dosage，different initiator and its dosage，reaction temperature and reaction time， and prepare the ternary grafting SBS adhesive of the bonding strength and the graft radio higher by solution polymerization．We found the optimized conditions of the craft is：the solvents are mixed solvents of toluene and carbon tetrachloride of the volume ratio as l：1． theinitialconcentration anddosageofS转Sis20％andthewight ratioofSBS、MMA、BA、 AA is 20：9：3：0．4．BPO is used as initiator,and its dosage is 2．5％of the monomer；the reaction time is five hours，and the reaction temperature is 80。C． The fact that the modified monomer react with the double bond of SBS were found through infrared spectral of SBS and its grafting copolymer．弧e mechanism of grafting copolymerization is BPO come into being the free radical by heated，then the flee radical come into being a large molecules free radical with SBS，at last this large molecule reacted with the grafting modified monomer and formed the grafting copolymer．SBS and PMMA were studied by TG the result is the decomposition temperature of the grafting copolymer is higher than that of SBS，as well，the product have high thermal stability．