三维有序大孔钛氧“锂离子筛”制备与吸附性能表征-无机化学专业论文.docxVIP

2009 2009 届硕士毕业论文： 三维有序大孔钛氧“锂离子筛”制备及吸附性能表征 II II Abstract Lithium and its compounds are even more widely applied in many aspects of our life with the development of science and technology. Absorption method has been considered the most promising way to uptake lithium from salt brines and seawater. The key technology of absorption method is preparation of the adsorbent with large saturation adsorption amount, good selective adsorptive properties, hi gh recycling rate. Synthesis of adsorbent with good selective adsorption to lithium ion is a very promising subject. The discourse includes three aspects: preparation of three-dimensionally ordered macroporous(3DOM) lithium titanium oxides Li4Ti5O12; extracting lithium ions from precursor to obtain lithium-ion sieve and characterization of its adsorptive property. Using methyl methacrylate (MMA) as monomer, polymethyl methacrylate (PMMA) emulsion colloidal microsphere with about 300nm diameter was successfully synthesized by emulsion polymerization. After centrifugation, PMMA colloidal crystal template was gotten. The precursor solution was prepared using LiAc·2H2O, TiCl4, oxalate, citric acid and ethanol. The PMMA colloidal crystal template was filled with the precursor solution. 3DOM Li4Ti5O12 was synthesized by roasting colloidal crystal template complex. Effect of stirring speed, initiator amount and reaction temperature on the diameter of colloidal microsphere was studied. The influence of the assembly of microsphere to the arrangement style of the colloidal crystal template was discussed. The impact of the property of precursor solution and calcination method to the structure of 3DOM was investigated. SEM images showed that four lithium tianium oxides arrayed as three-dimensional ordered macroporous skeleton and theirs diameter was between 100 and 130 nm. XRD indicated that the crystal phase of four lithium tianium oxides prepared under the different condition were mainly spinel Li4Ti5O12. The 3DOM Li4Ti5O12