锂离子电池正极材料的合成与电化学性能研究-应用化学专业论文.docxVIP

AbstractAbstract Abstract Abstract Spinel LiMn204 and layered LiNil／3COl／3Mnl／302 are promising cathode materials for lithium．ion batteries due to their advantages，such as high working voltage，high safety，low toxicity and low cost．But the low initial specific capacity and poor cycling performance prevent spinel LiMn204 from commercial application．Layered LiNiu3COl／3Mnl／302 still has the problem of rapid capacity reduction during cycling．In this dissertation，the cathode materials of spinel LiMn204 were synthesized by sol·gel method，multiple doping was used to improve the stability of spinel structure and cycling performance．The layered LiNil／3Col，3Mnl／302 were synthesized by different methods，the influence of structure and electrochemical properties were investigated．The charge—discharge cycling in high voltage region was researched． Studies of cation doping modification of spinel LiMn204 were conducted using Li+and Cr3+．The cathode materials Lil．osCrxMnl．95-x04(x=0，O．05，O．10，0．15)were synthesized by s01．gel method．The sintering temperatures were 650C、700C and 750。C respectively．111e synthesized materials were characterized with X—ray diffraction(XRD)and scanning electron microscope(SEM)．The electrochemical performances of the materials were tested by constant．current cycling in the room temperature(25。C)and the hilgh temperature(55。C)for 40 cycles．The results showed that the samples possessed pure spinel phase，good morphology and uniform distribution of grain size．The Lil．05Cro．iMnl．8504 powder with best performance call be obtained at sintering temperature 700℃for 1 2h，which initial specific discharge capacity were 1 1 3．7mAh／g and 1 1 4．2mAh／g．and the capacity retention were 94．2％and 89．7％after 40 cycles．It Was evident that multiple doping of Li+、Crj+Can improve the stability of spinel structure and cycling performance． The cathode materials LiAlo．05MxMnl．95．x03．95F0．05(x=O，O．01，0．05；M=Li，Co，Cr,Ni) were synthesized by sol-gel method．The materials possess