离子液体中空纤维液膜体系分离Cs的探索研究-安全技术及工程专业论文.docxVIP

西南科技大学硕士研究生学位论文 西南科技大学硕士研究生学位论文 第1页 摘 要 本文以Cs+为研究对象，选择卜丁基一3一甲基咪唑翁盐为溶剂，较系统 地进行了液一液溶剂萃取研究，并在此基础上，借鉴了支撑液膜、包容液膜 等非平衡传质技术的原理，综合了“绿色”稀释剂离子液体的优异特点，构 建新型的液膜体系，采用疏水性聚丙烯中空纤维作基膜、离子液体作膜溶剂、 DBl8C6作载体，研究了不同液膜过程分离提取Cs+的性能，初步探索离子液 体与液膜技术结合用于Cs+分离提取的应用潜力。液一液溶剂萃取研究显示 Cs+萃取率最高可达99．76％，但反萃难，其中水相初始Cs+浓度的影响显著， 实验结果表明该溶剂体系适合用于低浓度Cs+的萃取；结合液膜技术后，成 功制备了中空纤维支撑离子液体膜并实现了从含Mo溶液中回收80％的Cs， 但该膜过程稳定性控制难，重复性较差；研究显示封闭离子液体膜体系稳定 性好且省去了制膜过程，操作方便，其结构具有很大的调整弹性，实验结果 表明该膜体系适合用于痕量Cs的分离回收。膜过程后的离子液体基本稳定， 通过除杂提纯后可以再利用。 关键词： 离子液体 液膜技术 铯离子 回收 西南科技大学硕士研究生学位论文 西南科技大学硕士研究生学位论文 第lI页 Abst ract Ionic liquids(ILs)are emerging as alternative solvents for volatile organic compounds conventionally used in liquid．1iquid化．L)extraction and liquid membrane separation．In this paper，L．L extraction of Cs’was systematically studied with 1．butyl．3．methyl．imidazolium as solvent．Furthermore．a novel liquid membrane system integrated the advantages of“green”diluents，ionic liquids，Was proposed，in which non—equilibrium mass transfer theory Was used as reference．The potential application of integration of ionic liquid and membrane technique for Cs+separation and extraction Was preliminarily explored，in different membrane processes．using hydrophobic polypropylene hollow fiber．ionic liquid and DB 1 8C6 as basement membrane．membrane solvent and carrier respectively．L．L extraction results showed that a high extraction ratio of 99．76％could be obtained．However．stripping iS difficult and the extraction ratio was significantly affected bv iIlitial Cs+concentration in water phase。which indicated that the solvent system was iust suitable for the extraction of lOW Cs+concentration．WMle combining liquid membrane technique．all IL．based hollow fiber supported liquid membrane(IL—HFSLM)Was successfully prepared and fulfilled a recovery ratio of 80％for Cs+in molybdenum contained feed．However．the stability of IL．HFSLM iS uncontrollable under the conditions of this work．and the reproducibility of membrane process was poor．Compared、Ⅳith IL．HFSLM system．holl