十溴联苯醚的光降解及细胞毒性分析-环境科学专业论文.docxVIP

中央民族大学硕士研究生论文AB 中央民族大学硕士研究生论文 AB STRACT ⅢY iiii●I 洲8 ㈣2 ⅢⅢⅢ川●I 咖0 ㈣3 嗍2 BFR(brominated flame retardant)is all additive widely used in textiles and electronic items．In 20 1 0，the total production of flame．retardants will reach 2．0 x l 05 t in China．The greatest demand for PBDEs in the market is BDE209(DeBDE)．After dumped into environment, BDE209 produces low—brominated biphenyl ethers and is transformed into PBDD and PBDF after photolysis，pyrolysis，biological and microbiological degradation．The degradation products will get easier access entering into organisms and may cause heavier toxicity． The research consists of two parts： Part 1：The analysis of photochemical reaction of BDE209．On the basis of assertion of the BDE209 and its main photochemical primary products under the testing condition of the pure methanol as the mobile phase and the detection wavelength of 254nm，HPLC method to test the BDE209 and the three primary products is established．Through the photochemical degradation studies of BDE209 in four different solvents (degradation rate：chloroformDMSOnormal hexaneacetone)，all the four degradation processes follow the first—order kinetics；after observation of BDE209 added normal reagent，new synthetic nano—material copper oxide， new synthetic nano—material cuprous oxide and nano—material copper oxide and nano．material cuprous oxide after a time of deposit，the results show that copper oxide and cuprous oxide could accelerate BDE209 degradation III 中央民族大学硕士研究牛论文rate，and 中央民族大学硕士研究牛论文 rate，and all degradation processes follow first—order kinetics．The acceleration effects of nano—materials on BDE209 are obviously better than the ordinary copper oxide．The acceleration rates of different photosensitizers in the same concentration are：double layer nano．cuprous oxidesingle layer nano—cuprous oxidecopper oxidecuprous oxide．With time increasing of nano—materials’settlement，their degradation effect on BDE209 will weaken gradually． Part 2：BDE209 Cytotoxicity research．Firs