卤氧化铋化合物的制备及其光敏化分解罗丹明B的研究-应用化学专业论文.docx

南京航空航天大学硕士学位论文 南京航空航天大学硕士学位论文 万方数据 万方数据 ABSTRACT Bismuth oxyhalides of BiOX (X = Cl, Br, I) currently still attracts great attention because of their potential applications in solar light utilization (such as heterogeneous photocatalysis). In the thesis, a new preparation scheme of BiOX (X=Cl, Br, I) has been obtained through a reduction/oxidation-hydrolysis method, by using NaBiO3 and hydrogen halide solution as the starting materials. Based on the investigation of microstructure and optical properties of as-prepared samples, the sorption, photosensitized decomposition performance of Rhodamine B (selected as model contaminant) as well as the corresponding mechanisms has been studied. Furthermore, the activity-structure relationship between the photodegradation activity and frontier orbital energy of selected model contaminant has been preliminarily established. The main studies in the thesis are listed as follows, BiOX(X=Cl, Br, I) semiconductor compounds were prepared through a reduction/oxidation-hydrolysis method, using NaBiO3 and hydrogen halide solution as the starting materials. It was found that the diameters of as-prepared BiOCl, BiOBr and BiOI nanoplates were measured at around 690 nm，650 nm and 120 nm, respectively. Selected area electron diffraction analysis clearly showed the single crystalline characteristics of as-prepared BiOX nanoplates which are vertical to the c axis ([001] direction). UV-Vis diffuse reflectance indicated that the optical absorption of BiOX(X=Cl, Br, I) starts from 374 nm, 434 nm and 682 nm, respectively. The sorption kinetics, thermal dynamics and sorption isotherms of Rhodamine B onto BiOCl and BiOBr were studied. The sorption kinetics study showed that the pseudo-second-order kinetics model could fit the sorption data better than pseudo-first-order kinetics model. The results from Langmuir fitting suggest that the monolayer saturated sorption capacity of BiOCl (11.3 μmol g-1) is slightly lower than that of BiOBr (13.0 μmol g-1