两亲性星形三嵌段共聚物在稀溶液中的自组装-材料化学工程专业论文.docxVIP

ABSTRACT In the paper，using self-consistent field theory(SCFn method ，we make a study on t he self-assembly of a mphiphilic A BC s tar triblock c opolymer wi由 computer 、simulation. We m ain change chain 1ength 0 f A ，B，C blocks and the F lory Huggins interaction parameter with each other and then investigate the structures and the phase 、 behavior of micelles formed in three dimensions ，and then find some regulation and 由e process of some special structures formation. When we analysis chain length make what affect on phase separation，we found th创 when we only increase chain len部h and the other parameters are keep unchanged ，the interaction value of each other also incre剧院 the phase separation become more and more localization and also phase separation 0 ccurred m ore e asy. At the same t ime，we make compare with experiment， and found that the vesicles which wi由tail on the peak of its，this structures also f ound i n experiment ，but di fferent w ith t hem，unde r t his p町ameters conditions，the result calculated long enough time by computer，the structure is not the final stability structure，i s a i ntermediate transition s阳te. A nd t he s tructure i s disappeared final1y，chang from vesicles to 1ayers. And a t 由e 0 ther time ，novel muicellarstructures s uch a s v esicles c onnect w ith s trip w hich is d idnt found i n experiment ，these struc阳res have some predictive in experiments. h Keywords: amphiphilic; self-consistent field theory; ABC star triblock copolymers; self-assembly; 尊 目录 第一章文献综述.....…....………........…………………….........….......….............… ...........1 1.1 嵌段共聚物简介...............….........…..........…………..........… ...................1 1.2 嵌段共聚物自组装简介....................…..….........…..........…… ...................1 1.3 嵌段共聚物自组装的应用……........川......…….......................…........…·… 3 1.4 研究嵌段共聚物自组装的理论方法..................…........…...............…… 3 飞 1.4.1 强分相理论...........…........，....……….........….....…………..………..3 1.4.2 弱分相理论......