两亲性嵌段共聚物的合成及其用于热固性树脂在纳米尺度上微结构的控制-材料学专业论文.docxVIP

` ` A Dissertation Submitted to Shanghai Jiao Tong University for the Degree of Master Synthesis of amphiphilic block copolymer and control of Nanostructured Thermosetting Polymers Author：Li Lei Advisor：Zheng Sixun School of Chemistry and Chemical Engineering Shanghai Jiao Tong University Shanghai, P.R.China January 6, 2009 两亲性嵌段共聚物的合成及其用于 热固性树脂在纳米尺度上微结构的控制 摘 要 应用可逆加成—断裂链转移(RAFT)自由基聚合合成了一系列两亲性嵌段共 聚物，并运用核磁共振(NMR)、傅立叶红外光谱(FTIR)、凝胶色谱(GPC)对其 结构进行了表征。并对这些嵌段共聚物的形态结构、结晶性能进行了研究。 基于合成的嵌段共聚物的两亲性能，我们对其分别如下的应用：将三嵌段共 聚物聚四乙烯基吡啶 -b-聚甲基丙烯酸甲酯 -b-聚四乙烯基吡啶 (P4VP-b-PMMA-b-P4VP)在线型酚醛树脂固化，对固化前后的相结构进行了研 究，得到了纳米尺度上的微相分离。所得的热固性树脂经高温降解掉其中的嵌段 组分后，得到具有纳米孔的碳材料。将两亲性三嵌段共聚物聚甲基丙烯酰氧基三 乙氧基硅烷 -b-聚甲基丙烯酸甲酯 -b-聚甲基丙烯酰氧基三乙氧基硅烷 (PTMSPMA-b-PMMA-b-PTMSPMA)与正硅酸乙酯(TEOS)混合，经溶胶凝胶， 高温降解，得到具有纳米孔的二氧化硅材料。应用反应将无机元素硅引入嵌段共 聚物(PGMA-b-PMMA-b-PGMA)中，得到两亲性有机/无机两亲性嵌段共聚物， 经溶胶凝胶，高温降解，得到具有纳米孔的二氧化硅材料。将双亲水性接枝共聚 物聚乙烯亚胺-g-聚环氧乙烷(PEI-g-PEO)与α-环糊精进行络合，得到双亲性超分 子络合物。 关键词：可逆加成—断裂链转移，两亲性嵌段共聚物，微相分离，纳米孔材料 Synthesis of amphiphilic block copolymer and control of Nanostructured Thermosetting Polymers ABSTRACT A series of amphiphilic block copolymers were synthesized by RAFT polymerization. The structures were investigated by NMR, FTIR, GPC and the crystallization and stability were characterized. According to the characterization of their amphiphilic block copolymer, we applied for the following facts: P4VP-b-PMMA-b-P4VP triblock copolymer was used to incorporate into phenolic resin to afford the nanostructured thermosets. The results showed that the regular nanostructures were obtained reacted induced microphase separation. Meanwhile, the nanoporous carbon material was obtained by heating. PTMSPMA-b-PMMA-b- PTMSPMA triblock copolymer was blended with TEOS and the nanoporous Silicone materials were obtained by the sol-gel process and heating to a high temperature. PGMA-b-PMMA-b-PGMA triblock copolymer was reacted with aminopropyltriethoxysilane to obtain the organic/inorganic block copolymer. The organic/inorganic block copolyme was blended wit