硫酸氢酯化富勒烯醇的合成及其性能研究-分析化学专业论文.docxVIP

西南科技大学硕士研究生学位论文 西南科技大学硕士研究生学位论文 第1页 摘 要 本论文主要包括三部分：硫酸氢酯化的富勒烯醇的合成表征及其工艺研 究、Nation／硫酸氢酯化富勒烯醇复合膜的制备及其表征、Nation／硫酸氢酯化 富勒烯醇复合膜的基本性能研究。 以自制富勒烯C60、NaOH、H202以及发烟硫酸通过亲核取代反应合成 了硫酸氢酯化的富勒烯醇，并用FT—IR、MS和元素分析等测试手段对其结 构进行了表征。研究并获得了硫酸氢酯化富勒烯醇的最佳合成工艺条件：反 应物富勒烯醇、20％发烟硫酸的物质的量比为1：11，反应温度为25℃，反 应时间为72h，此时硫酸氢酯化富勒烯醇产率可达到52．2％。采用共混法首 次制备了Nafion／C60(OS03H)7(OH)ll复合膜，并对其结构进行了表征，结果 表明，Nafion／C60(0803H)7(OH)11复合膜和Nation膜的骨架基本一致，且复 合膜内部分散比较均匀，没有发生团聚现象。对Nation／硫酸氢酯化富勒烯 醇复合膜的基本性能进行了研究测试，结果表明，复合膜具有优良的保水性 能、良好的稳定性和较优的质子导电性能。 关键词：硫酸氢酯化富勒烯醇 合成 复合膜 结构表征 性 能研究 AbstractThis Abstract This thesis includes three parts，synthesis and characterization of hydrogen sulfate ester fullerene，preparation and technology of hydrogen sulfate ester fullerene alcohol／Nation composite membrane and its performance study． Ethanol hydrogen sulfate ester fullerene was prepared by fuming sulfuric acid and fullerene alcohol which was synthesized by C60，sodium hydroxide and sodium hydroxide as a oxidizing agent．The samples were characterized by Fourier transform infrared，mass spectroscopy and elemental analysis．We had investigated the effects of reactant ratio，reaction temperature and reaction time． The results indicated that the best synthesis conditions for the product 2 were： the temperature was 25℃，reaction time was 72h，while the fullerene alcoh01 to the_29wt％fuming sulfuric acid mole ratio was 1：1 1 and the product 2 may yield up to 52．2％．Ethanol hydrogen sulfate ester fullerene／Nation composite proton exchange membrane was firstly prepared via a blending method using hydrogen sulfate ester fullerene blend ethanol and Nation solution．The analysis indicated that carbon nano．materials distribution in the membrane had no reunion．The basic effects of hydrogen sulfate esterfullerene alcohol／Nation composite proton exchange membrane had been studied，the results showed this membrane had excellent water retention properties，good stability and optimum performance of the proton conductivity． Key words：hydrogen sulfate etheritication