磷酸铁锂包覆特性研究-材料物理与化学专业论文.docxVIP

磷酸铁锂包覆特性研究 磷酸铁锂包覆特性研究 河北工业大学硕士学位论文 河北工业大学硕士学位论文 ii ii STUDY ON COATING CHARACTERISTICS OF LITHIUM IRON PHOSPHATE ABSTRACT For the existing problems in the modification of LiFePO4 cathode materia, such as coating process complex, carbon-coated uneven and particle size too large and so on, using starch as carbon source, which can be heated to form a stable colloid achieving the uniform coated precursor. Superfine LiFePO4/C composite material was synthesized by carbothermal reduction. The electrochemical performances were evaluated by the programmable constant-current charge-discharge test system. The structure and morphology of material were characterized by means of X-ray diffraction (XRD), Scanning electron microscope (SEM), Transmission electron microscope (TEM), and Thermogravimetry/differential thermal analysis (TG-DTA). The effect of calcining temperature and time synthetic process parameters was investigated. The best synthetic conditions were determined by the orthogonal experiment. And the study was done on the high-performance LiFePO4/C composite material synthesized by carbothermal reduction with using composite carbon sources. It was found that LiFePO4/C composite material synthesized by using starch as carbon source not only had superfine spherical particle morphology, a particle size of about 500nm, but also the particle surface of which was coated by the network filaceous conductive carbon evenly. Compared with traditional solid-phase coating process, not only it reduced the particle size, but also effectively reduced polarization to improve the electrochemical performance of LiFePO4. The best synthetic process conditions determined by the orthogonal experiment are as follows: calcining temperature: 750℃, calcining time: 4h, the ratio of doped carbon: FePO4: Li2CO3: C=2: 1.02: 2. The LiFePO4/C composite material synthesized under the best synthetic process conditions had good crystalline, high specific conductance (5.12×10-2S/m) and tap density (1.25