磷酸钙骨水泥强度的研究-材料学专业论文.docxVIP

中文摘要磷酸钙骨水泥(CPC)是一种非常有应用前景的齿科和整形外科修复材料。 中文摘要 磷酸钙骨水泥(CPC)是一种非常有应用前景的齿科和整形外科修复材料。 由于其与水混合后的白固化性能，如今CPC引起了人们的广泛重视。目前磷酸 钙骨水泥(CPC)的脆性大和强度低限制其在很多承受应力部位或骨质薄弱部位 的应用，提高骨水泥的机械性能是扩展骨水泥应用范围的重要方面。 本文中，采用m磷酸三钙(a-TCP)和磷酸四钙(TTCP)作为水泥的固相 组分，液相由磷酸氢二钠和／或柠檬酸与水组成。测量了水泥的抗压强度和孔隙 率。考察了固相组分颗粒尺寸、液周比(I_口)和固化液组成等对骨水泥抗压强 度的影响。 实验结果表明，原料颗粒尺寸对水泥抗压强度没有明显的规律性；抗压强度 随着固化液pH值的减小而增大；对于液固比，存在一个最佳值，在该点抗压强 度获得最大值。对于采用湿法合成的a-TCP的试样，在I．／P=0．30mUg和pH=5 的条件下，获得最高强度21．69MPa。 另外，单纯以水和磷酸氢二钠、柠檬酸为固化液的磷酸钙骨水泥不够粘稠， 并且在固化前易于被冲刷掉。本文还考察了在酸、碱两种固化液中加入黄原胶对 骨水泥抗冲刷性能、固化行为、和机械性能等的影响。结果表明，黄原胶可以提 高骨水泥的抗冲刷性能。 关键词：a-TCP，骨水泥，抗压强度，孔隙率，黄原胶 ABSTI认CTCalcium ABSTI认CT Calcium phosphate cement(cPc)is a kind of promising materials used in dental and orthopeadic restoration．Nowadays，CPC is of special interest due to its self-setting behavior when mixed with all aqueous liquid phase．Currently,the high briHleuess and low strength of calcium phosphate cement(o,63 restrict its application in many load-bearing and weak bone sites；it is important to improve the mechanical strength of CPC to expand its application． In this study,a-tricalcium phosphate(a-TCP)and tetracalcium phosphate frro,)were served as the solid component of the cement,and the liquid component was consist’of sodium phosphate dibasic dedocahydrate(Na2HP04．12H20)，and／or citfic acid．The cements properties鸹compressive strength and porosity were measured．The effects of preparing conditions，such as particle size of the solid component,liquid—to—powder ratio(L／P)and liquid composition,on compressive strength of calcium phosphate were investigated． The results show that the particle size of a-TCP has nO obvious regularity on the compressive strength of the cement．The compressive strength increases with the decreasing of setting liquid’S pH value．There is a premium L伊in which the compressive strength gains its maxim．The compressive strength reached 21．69MPa at the condition of I．／P--0．30mL／g and pH=5 in the sample that employs wet-method synthesized a-TCP． However,the water-based CPC pas