快速成型用光敏树脂的分析-机械制造及其自动化专业论文.docxVIP

硕士论文 硕士论文 快速成型用光敏树脂的研究 摘要 K锄5‘3 环氧丙烯酸(EA)树脂在快速成型领域中是一种重要的感光树脂。实验研究了这 种树脂的合成工艺，讨论了原料投料比、反应温度、催化剂及操作方法等因素对树脂 性能的影响并对其进行数学拟合；实验通过各项性能测量和正交化实验，确定光固化 体系的最佳反应条件。 采用双羟基化合物聚乙二醇与环氧树脂进行反应，制取低粘度的改性环氧树脂， 然后经丙烯酸酯化，制得低粘度的紫外光固化快速成型用环氧丙烯酸酯预聚物。研究 了双羟基化合物与环氧树脂的当量比、催化剂的类型、催化剂的用量、反应温度及反 应时间对反应及产物性能的影响，确定环氧树脂改性反应和丙烯酸酯化反应的最佳条 件。制得的改性预聚物固化后经FT—IR和TB／DGA等表征成型性能得到了改善。 关键词：快速成型光敏树脂紫外光固化 光引发剂 双羟基化合物 硕士论文 硕士论文 快速成型用光敏树脂的研究 Abstract Epoxy acrylate(EA)resin is an important photosensitive resint in which bisphonolic epoxide was most widely used in the field of Rapid Protoyting。The synthesis process of EA resin was studied。Influences of ratio of reacting material，selection of catalyst and reaction temperature on the resin properties were discussed。The article described the priciples ofradition curing process，formulation ofuV curing coatings，selection ofli曲t sources and raw materials．Reaction conditions were optimized by orthogonal test。 ‘ At the second part of this papers，a low viscosity modified epoxy resin has been prepared based on the reaction epoxy resin with dihydroxyl compound polyethylene glycol，then esterified with acrylicacid to form a low viscosity epoxy acrylate for UV—curing a The influence of ratio of dihydroxyl compound and epoxy resin，types of catalyst，amount ofcatalyst，一reaction temperature and reaction time on the two reaction and properties of epoxy acrylate has been discussed。The optimum reaction conditions for epoxy modification and esterification with acrylic acid are given。By means of FT—IR and TG／DGA and other Characteristic methods，a cured insoluble material showing increased hardness，flexibility and erodent resistance has been formed by a short UV—irradiation of blends ofmodified epoxy acrylate，active monomer and photoinitiator。 Key words：Rapid Prototyping Photosensitive Resin Ultraviolet curing Photoinitiator Dihydroxyl Compound 硕士论文 硕士论文 快速成型用光敏树脂的研究 1绪论 1．1快速成型技术发展概况 随着科学技术的发展和社会需求的多样化，产品的竞争越来越激烈，更新的周期 也越来越短，因而要求设计者不但能根据市场的要求设计新产品，而且能在尽可能短 的时间内制造出原型，从而进行必要的性能测试，同时在