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Study on Elect rodeposit ion of Lowstr es s N iCo
A lloy Coat ing in Sulfat e Bath
, , ,
( , 100 124
WA N G Y an , L EI Y ongping, FU H anguang , L IN J ian
( College of Mat erials Science and Eng ineer ing,
Beijing U niversit y of T echno logy , Beijing 100124, China
:
: , , ( 111
, ; , 0 . 0 8g / L 2g/ L
, 64. 64 M Pa - 3. 5M P a,
: ; ; ; ;
: T G 14 6. 1; T G17 : A : 100 14 381( 2010 0800 1604
Abstract: L owst ress N iCo alloy co at ings w ere obt ained in sulfat e bat h by adding proper am ount of
but ynediol and saccharin. T he ef fect of buty nedio l and saccharin concent rat io n on cro sssectio n mo r
pholog y, micro hardness, st ruct ure and int ernal st ress of t he co at ing w as invest igat ed. T he r esults
show ed that but y nediol and saccharin could lead to f iner grain, higher micro hardness and str ong er
( 111 plane. But ynediol could produce the coat ing co nt ract ion and t ensile st ress , w hile saccharin
could produce t he coating ex pansion and co mpressive st ress. T he co at ing int ernal str ess r ange f rom
6464MP a t o - 3. 5M Pa by adding 0. 0 8g/ L buty nediol and 2g / L sacchar in t o t he sulf at e bat h , and the
coat ing had hig h micr ohar dness and quality .
Key words: sulfat e bat h ; but y nediol; saccharin ; internal str ess; m icrohardness
, COSO4 7H 2 O , 40g/ L H BO3 , 15g/ L N aCl, 0 . 08g / L
80 % , , 50 , p H 4,
2
4A/ dm pH
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