2,5-二甲基四氢呋喃低压热解实验和动力学模型研究.docxVIP

基金项目：国家自然科学基金(No.51706217) 中国工程热物理学会 燃烧学 学术会议论文 编号：184040 2,5-二甲基四氢呋喃低压热解实验和动力学模型研究 王乾鹏1，唐幸炎1，杨玖重3，张言3，曹创创3，翟翌童3，王娟1,2,* （1 北京航空航天大学能源与动力工程学院，北京 100083; 2 北京航空航天大学能源与动力工程学院航空发动机气动热力国家级重点实验室，北京 100083; 3 中国科学技术大学国家同步辐射实验室，安徽 合肥 230029) (* Tel:010 Email: juanwang@) 摘 要 2,5-二甲基四氢呋喃是一种非常有应用潜力的生物质燃料。本文利用同步辐射真空紫外光电离质谱(SVUV-PIMS)技术，研究了2,5-二甲基四氢呋喃在压力为30 Torr、温度从948到1198 K条件下的流动管热解反应。实验探测到了包括自由基和稳定产物在内的四十余种物种，基于实验结果，提出了一个由264个物种和1488个反应组成的动力学模型，并利用实验结果进行了验证；通过生成速率分析，得到了燃料的初级解离过程和主要热解产物的生成路径。 关键词 2,5-二甲基四氢呋喃；流动反应器热解；同步辐射真空紫外光电离质谱；燃烧反应动力学 Low Pressure Pyrolysis Experiment and Kinetic Modeling Study of 2,5-Dimethyltetrahydrofuran WANG Qianpeng1, TANG Xingyan1, YANG Jiuzhong3, ZHANG Yan3, CAO Chuangchuang3, ZHAI Yitong3, WANG Juan1,2* (1 School of Energy and Power Engineering, Beihang University, Beijing 100083; China; 2 National Key Laboratory of Science and Technology on Aero-Engine Aero-thermodynamics, School of Energy and Power Engineering, Beihang University, Beijing 100083; China; 3 National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, China) Abstract 2,5-dimethyltetrahydrofuran is considered as a very promising biomass fuel. In this study, the pyrolysis of 2,5-dimethyltetrahydrofuran was studied in a flow reactor using synchrotron vacuum ultraviolet photoionization mass spectrometry (SVUV-PIMS) at the pressure of 30 Torr and the temperatures from 948 to 1198 K. More than 40 pyrolysis species were identified and their mole fraction profiles were measured as a function of temperature, including stable products and several free radicals. Based on the experimental results, a detailed kinetic model consisting of 264 species and 1488 reactions was proposed and verified using the experimental results. Besides, by rate of production analysis, the primary dissociation process of th